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Merck

144908

Sigma-Aldrich

2-氨基-4-甲基苯酚

97%

别名:

2-氨基对甲酚, 2-羟基-5-甲基苯胺, 3-氨基-4-羟基甲苯

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About This Item

线性分子式:
H2NC6H3(CH3)OH
CAS号:
分子量:
123.15
Beilstein:
606494
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

形狀

solid

mp

133-136 °C (lit.)

SMILES 字串

Cc1ccc(O)c(N)c1

InChI

1S/C7H9NO/c1-5-2-3-7(9)6(8)4-5/h2-4,9H,8H2,1H3

InChI 密鑰

ZMXYNJXDULEQCK-UHFFFAOYSA-N

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一般說明

2-氨基-4-甲酚是联系分散黄 3 接触过敏的主要致敏剂 。它与乙酰丙酮在无水乙醇中反应生成 4-(2-羟基-5-甲基苯基)亚氨基-2-戊酮 。用纯化的人血红蛋白转化为二氢吩恶嗪酮

應用

2-氨基-4-甲基苯酚被用于合成 2 H -1,3-苯并恶嗪酮系列的新型功能化螺吡喃衍生物

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Hongmei Peng et al.
Inorganic chemistry, 47(21), 9828-9835 (2008-10-03)
The synthesis and reactivity of a series of sodium and rare-earth metal complexes stabilized by a dianionic N-aryloxo-functionalized beta-ketoiminate ligand were presented. The reaction of acetylacetone with 1 equiv of 2-amino-4-methylphenol in absolute ethanol gave the compound 4-(2-hydroxy-5-methylphenyl)imino-2-pentanone (LH2, 1)
Antony O Bulanov et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 71(3), 1146-1152 (2008-06-14)
Six novel functionalized spiropyran's derivatives of 2H-1,3-benzoxazinone series were synthesized by introducing the substituents with chelating ability into 2H-chromene part of the 8'-formyl-7'-hydroxy-3-methyl-4-oxo-3,4-dihydro-2H-1,3-benzoxazine-2-spiro-2'-[2H]-chromene (I) by condensation with 2-aminophenol, 2-amino-4-methylphenol, 2-amino-4-nitrophenol, 2-amino-1-methylbenzimidazole, 4-amino-4H-1,2,4-triazole, N-(4-aminophenyl)acetamide. (1)H NMR, UV/vis, IR spectroscopy combined with
A Tomoda et al.
Journal of biochemistry, 110(6), 1004-1007 (1991-12-01)
2-Amino-4-methylphenol was converted to a brownish yellow material by the lysates of human erythrocytes or purified human hemoglobin. The reaction proceeded oxidatively, coupled with the oxidation of hemoglobin. The major component of the brownish yellow material produced by oxidative condensation
Z He et al.
Applied and environmental microbiology, 66(7), 3010-3015 (2000-07-06)
In spite of the variety of initial reactions, the aerobic biodegradation of aromatic compounds generally yields dihydroxy intermediates for ring cleavage. Recent investigation of the degradation of nitroaromatic compounds revealed that some nitroaromatic compounds are initially converted to 2-aminophenol rather
M Akazawa et al.
The Tohoku journal of experimental medicine, 192(4), 301-312 (2001-04-05)
When human erythrocytes were incubated with o-aminophenol at pH 7.0 at 37 degrees C for 46 hours, intracellular oxyhemoglobin was completely oxidized to methemoglobin during the initial 6 hours, and methemoglobin formed was then reduced to oxyhemoglobin during the following

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