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Merck

907065

Sigma-Aldrich

聚TPD

greener alternative

Mw ≥20,000 g/mol

别名:

4-丁基-N,N-二苯胺均聚物, Poly(4-丁基-N,N-二苯胺), 聚(4-丁基三苯胺), 聚[N,N′-双(4-丁苯基) -N,N′-双(苯基)-联苯胺]

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1 G
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About This Item

线性分子式:
(C22H21N)n
MDL编号:
UNSPSC代码:
12162002
NACRES:
NA.23

$652.00


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描述

Solution processable

表单

powder

分子量

Mw ≥20,000 g/mol

环保替代产品特性

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

>300 °C

轨道能量

HOMO -5.2 eV 
LUMO -2.4 eV 

环保替代产品分类

储存温度

15-25°C

一般描述

我们竭诚为您带来绿色替代产品,以确保符合一项或多项绿色化学12项原则要求。本品属于绿色替代产品的赋能型产品,符合“节能设计”原则。空穴传输有机材料与吸收层的能级排列完美匹配,因此实现高效的电荷收集,它在环境条件下易于降解。点击此处 了解更多信息。

应用

在最近的一项双结量子点发光二极管(QD-LED)的研究中,获得了42.2%的高量子效率和183.3 cd/A的高电流效率,令人印象深刻,可媲美最好的真空沉积串联有机LED。这种高效器件是通过完全优化的单发光单元界面工程实现的,它改善了载流子输运/注入平衡,抑制了ZnO诱导的激子猝灭,并设计了由聚TPD混合聚(9-乙烯基卡咪唑)(PVK)/聚(3,4-乙烯二氧噻吩):聚苯乙烯磺酸盐/聚乙烯亚胺乙氧基化修饰ZnO组成的有效互连层。[1]

室内光伏是最佳可持续和可靠能源之一,适合快速发展的物联网等低功耗电子产品。
在最近的另一项研究中,具有介孔PPV (mPPV)结构的钙钛矿光伏(PPV)电池采用典型的Spiro-OMeTAD作为空穴传输层(HTL),在200勒克丝下的最大功率密度(Pmax)为19.9 μW/cm2,在1000勒克丝(无掩蔽)下的最大功率密度(Pmax)为115.6 μWcm-2,堪称最好的室内PV之一。当用聚TPD代替PEDOT:PSS作为倒置PPV (iPPV)电池的HTL时,室内光照下的Pmax明显提高,可媲美最佳介孔mPPV电池。[2]


设备性能:
iPPV-聚TPD
1. 在阳光下[Pin=100 mW/cm2]
Jsc=21.8 mA/cm2
Voc=1.07 V
FF=73.7%
PCE=17.2%

2. 1000 lux下 [200 lux]
Jsc=172.3 mA/cm2
Voc=0.851 V
FF=75.9%
Pmax=111.3 mW/cm
聚TPD是一种溶液可加工的聚合物空穴传输材料。其应用包括:
  • 有机发光二极管(OLED):空穴传输层/电子阻挡层(HTL/EBL)材料
  • 溶液可加工OLED:聚合物空穴传输层
  • 染料敏化太阳能电池(DSSC):空穴传输材料
  • 钙钛矿太阳能电池:空穴传输材料
  • 柔性印刷电子产品:孔传输层/孔注入层(HTL/HIL)聚合物

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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其他客户在看

Piaoyang Shen et al.
ACS applied materials & interfaces, 11(1), 1065-1070 (2018-12-20)
Despite the rapid development in quantum-dot light-emitting diodes (QD-LEDs) with a single junction, it remains a big challenge to make tandem QD-LEDs with high performance. Here, we report solution-processed double-junction tandem QD-LEDs with a high external quantum efficiency of 42.2%
Outstanding Indoor Performance of Perovskite Photovoltaic Cells - Effect of Device Architectures and Interlayers.
Lee H K H, et al.
Solar RRL, 3(1), 1800207-1800207 (2019)

商品

Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

Questions

1–3 of 3 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  3. 해당 물질의 용액 제작에 어떤 solvent 사용하는지 알고 싶습니다.

    1 answer
    1. This product has not been tested for solubility. However, various sources state that this chemical can be solubilized in chloroform or chlorobenzene. The concentrations at which it can be solubilized are not determined.

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