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Merck

901423

Sigma-Aldrich

ITIC-F

别名:

9-Bis(2-methylene-((3-(1,1-dicyanomethylene)-6,7-difluoro)-indanone))-5,5,11,11-tetrakis(4-hexylphenyl)-dithieno[2,3-d:2’,3’-d’]-s-indaceno[1,2-b:5,6-b’]dithiophene, IT-4F, ITIC-2F, ITIC-DF3

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100 MG
$974.00

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预计发货时间2025年6月24日详情


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100 MG
$974.00

About This Item

经验公式(希尔记法):
C94H78F4N4O2S4
分子量:
1499.90
MDL编号:
UNSPSC代码:
12352101
NACRES:
NA.23

$974.00


预计发货时间2025年6月24日详情


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描述

Band gap: 1.52 eV

质量水平

方案

97%

表单

solid

轨道能量

HOMO -5.66 eV 
LUMO -4.14 eV 

SMILES字符串

Fc1cc2c(cc1F)C(=C(C#N)C#N)\C(=C\c3[s]c4c([s]c5c4C(c8c5cc9c(c8)c%10[s]c%11c([s]c(c%11)\C=C%14/C(=O)c%15c(cc(c(c%15)F)F)C/%14=C(C#N)C#N)c%10C9(c%13ccc(cc%13)CCCCCC)c%12ccc(cc%12)CCCCCC)(c7ccc(cc7)CCCCCC)c6ccc(cc6)CCCCCC)c3)\C2=O

InChI

1S/C94H78F4N4O2S4/c1-5-9-13-17-21-55-25-33-61(34-26-55)93(62-35-27-56(28-36-62)22-18-14-10-6-2)75-45-72-76(46-71(75)89-85(93)91-81(107-89)43-65(105-91)41-73-83(59(51-99)52-100)67-47-77(95)79(97)49-69(67)87(73)103)94(63-37-29-57(30-38-63)23-19-15-11-7-3,64

InChI key

JOZQXSUYCMNTCH-ODDCUFEPSA-N

应用

ITIC-F can be employed as the electron transport layer (ETL) in OFET devices. It can be blended with donor polymers to form the active layer in p-type OFETs. ITIC-F exhibits a broad absorption spectrum that extends into the visible and near-infrared regions. This characteristic allows for effective light absorption across a wide range of wavelengths and contributes to enhanced light-harvesting and power conversion efficiency in OPV devices. ITIC-F is commonly used as a non-fullerene acceptor in OPV devices. It serves as the electron acceptor material alongside a donor polymer in the photoactive layer.
ITIC-F is a derivative of ITIC possessing lower energy levels and a broader absorption spectrum. It is used as an n-type molecule for organic photovoltaics, allowing very high performances of over 13%.
ITIC-F is a non-fullerene acceptor molecule, which can be used in the fabrication of organic solar cells (OSCs) and organic photovoltaics (OPVs).[1][2][3]

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable


历史批次信息供参考:

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其他客户在看

Performance limitations in thieno [3, 4-c] pyrrole-4, 6-dione-based polymer: ITIC solar cells
Yang F, et al.
Physical Chemistry Chemical Physics, 19(35), 23990-23998 (2017)
Efficient Non-Fullerene Organic Photovoltaic Modules Incorporating As-Cast and Thickness-Insensitive Photoactive Layers
Zhang T, et al.
Advanced Energy Materials, 8(25), 1801387-1801387 (2018)
Wenchao Zhao et al.
Journal of the American Chemical Society, 139(21), 7148-7151 (2017-05-18)
A new polymer donor (PBDB-T-SF) and a new small molecule acceptor (IT-4F) for fullerene-free organic solar cells (OSCs) were designed and synthesized. The influences of fluorination on the absorption spectra, molecular energy levels, and charge mobilities of the donor and
Highly efficient inverted ternary organic solar cells with polymer fullerene-free acceptor as a third component material
Zhang K, et al.
Journal of Power Sources, 413(35), 391-398 (2019)

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Professor Chen (Nankai University, China) and his team explain the strategies behind their recent record-breaking organic solar cells, reaching a power conversion efficiency of 17.3%.

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