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Merck
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主要文件

901267

Sigma-Aldrich

Hexamethylborazine

≥95%

别名:

1,2,3,4,5,6-Hexamethyl-1,3,5,2,4,6-triazatriborinane

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250 MG
$247.00
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$595.00

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250 MG
$247.00
1 G
$595.00

About This Item

经验公式（希尔记法）:
C6H18B3N3
CAS号:
877-07-6
分子量:
164.66
MDL编号:
MFCD00161355
UNSPSC代码:
12161600
NACRES:
NA.22

$247.00

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质量水平

100

方案

≥95%

表单

powder or crystals

反应适用性

core: boron
reagent type: catalyst

mp

99 °C

储存温度

−20°C

SMILES字符串

B1(N(B(N(B(N1C)C)C)C)C)C

InChI

1S/C6H18B3N3/c1-7-10(4)8(2)12(6)9(3)11(7)5/h1-6H3

InChI key

LCHQMXUQYONIOI-UHFFFAOYSA-N

应用

Hexamethylborazine has been developed by the Szymczak lab[1] for the delivery of alkyl and hydride nucleophiles[2] in addition to being a key component in the synthesis of recyclable trifluoromethylation reagents.[3][4]

其他说明

Recyclable Trifluoromethylation Reagents from Fluoroform

Manganese-mediated hydride delivery to a borazine by stepwise reduction and protonation

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCV8800
MKCW6231

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氮化硼试剂 powder, ~1 μm, 98%

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Sigma-Aldrich

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Tyler J Carter et al.
Angewandte Chemie (International ed. in English), 51(52), 13168-13172 (2012-11-20)
Recharging spent BN fuel: {Cr(CO)(3)} mediates the reduction of borazines by hydride and methyl nucleophiles to generate anionic complexes of dearomatized hexamethylborazine. Subsequent quenching leads to the release of a substituted cyclotriborazane, successfully demonstrating the stepwise reduction of a B=N
Borazine?CF3? Adducts for Rapid, Room Temperature, and Broad Scope Trifluoromethylation.
Geri J B, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 130(5), 1395-1399 (2018)
Reduction of Borazines Mediated by Low?Valent Chromium Species.
Carter T J, et al.
Angewandte Chemie (International Edition in English), 51(52), 13168-13172 (2012)
Manganese-mediated hydride delivery to a borazine by stepwise reduction and protonation.
Carter TJ, et al.
Organometallics, 33 (7), 1540-1543 (2014)
Manganese-Mediated Hydride Delivery to a Borazine by Stepwise Reduction and Protonation.
Carter T J, et al.
Organometallics, 33(7), 1540-1543 (2014)
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