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文件

901117

trans-Bis(tricyclopentylphosphine)(2-methylphenyl)nickel(II) chloride

Name: <I>trans</I>-Bis(tricyclopentylphosphine)(2-methylphenyl)nickel(II) chloride
Brand: ALDRICH

别名:

trans-(PCyp₃)₂Ni(o-tolyl)Cl

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About This Item

经验公式（希尔记法）:

C₃₇H₆₁ClNiP₂

CAS号:

1594112-85-2

分子量:

661.97

分類程式碼代碼:

12352200

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形狀

powder or solid

反應適用性

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

156-161 °C

SMILES 字串

CC1=[C-]C=CC=C1.P(C2CCCC2)(C3CCCC3)C4CCCC4.P(C5CCCC5)(C6CCCC6)C7CCCC7.[Ni+2].[Cl-]

應用

The following Ni complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)₂, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)₂. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)₂.

其他說明

法律資訊

Patent application PCT/US2014/064565. Sold under license from the Massachusetts Institute of Technology.

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Buss B L, et al.

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