775258

Grubbs Catalyst^® M202

Umicore

• 别名: Grubbs Catalyst^® M2, Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](3-phenyl-1H-inden-1-ylidene)(tricyclohexylphosphine)ruthenium(II)
• 经验公式（希尔记法）: C₅₄H₆₉Cl₂N₂PRu
• CAS号: 536724-67-1
• 分子量: 949.09
• MDL编号: MFCD08667892
• UNSPSC代码: 12161600
• PubChem化学物质编号: 329767745
• NACRES: NA.22

属性

• 质量水平: 100
• 表单: powder
• 反应适用性: core: ruthenium; reagent type: catalyst
• mp: 159 (d)-162 °C
• 储存温度: 2-8°C
• SMILES字符串: [Ru+2](=C7N(CCN7c9c(cc(cc9C)C)C)c8c(cc(cc8C)C)C)=C4c5c(cccc5)C(=C4)c6ccccc6.P(C3CCCCC3)(C2CCCCC2)C1CCCCC1.[Cl-].[Cl-]
• InChI: 1S/C21H26N2.C18H33P.C15H10.2ClH.Ru/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2-6-12(7-3-1)15-11-10-13-8-4-5-9-14(13)15;;;/h9-12H,7-8H2,1-6H3;16-18H,1-15H2;1-9,11H;2*1H;/q;;;;;+2/p-2
• InChI key: MCNUJWCJGIGFBS-UHFFFAOYSA-L

说明

应用

• Oxa-Cages Synthesis: Grubbs Catalyst® M202 is utilized in a synthetic approach for creating diverse oxa-cages via olefin metathesis, enhancing the scope of organic synthesis with high selectivity and efficiency in forming complex cyclic structures (Kotha et al., 2024).
• Phosphoproline Analogues: This article details the stereocontrolled synthesis of complex bicyclic systems, a type of chemical transformation where Grubbs Catalyst® M202 could potentially be applied for enhancing reaction pathways and outcomes in pharmaceutical synthesis (Hernández-Benítez et al., 2024).

法律信息

Product of Umicore

Product License
This product, its manufacturing or use, is the subject of one or more issued or pending U.S. Patents (and foreign equivalents) owned or controlled by Umicore PMC. The purchase of this product from Umicore PMC through Sigma-Aldrich, its affiliates or their authorized distributors conveys to the buyer a limited, one-time, non-exclusive, non-transferable, non-assignable license. Buyer′s use of this product may infringe patents owned or controlled by third parties. It is the sole responsibility of buyer to ensure that its use of the product does not infringe the patent rights of third parties or exceed the scope of the license granted herein.

For any further information on product please refer to your local Umicore PMC contact at http://www.pmc.umicore.com

Grubbs Catalyst is a registered trademark of Umicore AG & Co. KG

安全信息

• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable