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745022

Sigma-Aldrich

9-甲基-9H-芴-9-羰基氯

≥99.0% (GC)

别名:

COgen, 9-Methylfluorene-9-carbonyl chloride

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$262.00
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$1,220.00

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5 G
$262.00
25 G
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About This Item

经验公式（希尔记法）:
C15H11ClO
CAS号:
82102-37-2
分子量:
242.70
Beilstein:
5266487
MDL编号:
MFCD18839248
UNSPSC代码:
12352005
PubChem化学物质编号:
329765723
NACRES:
NA.22

$262.00

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方案

≥99.0% (GC)

表单

solid

反应适用性

reaction type: C-C Bond Formation

官能团

acyl chloride

SMILES字符串

CC1(C(Cl)=O)c2ccccc2-c3ccccc13

InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3

InChI key

ZQYOOHGEBHBNTP-UHFFFAOYSA-N

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应用

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

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Frequently Asked Questions are available for this Product.

象形图

Corrosion
GHS05

警示用语：

Danger

危险声明

H314

危险分类

Eye Dam. 1 - Skin Corr. 1B

储存分类代码

8A - Combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
BCCL8388
BCCM4551
BCCK4341
BCCC4751
BCCH2798

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[14C]-Carbon Monoxide
Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)
Philippe Hermange et al.
Organic letters, 13(9), 2444-2447 (2011-04-08)
A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of
Mia N Burhardt et al.
The Journal of organic chemistry, 77(12), 5357-5363 (2012-05-23)
We have synthesized two isotopically labeled variants of the β-amyloid binding compound FSB possessing (13)C-labels on the two terminal aryl carboxylic acid moieties. One of these was also fully deuterated on the olefinic spacers. The (13)C-isotope labeling was achieved applying
Korsager, S.;
Angewandte Chemie (International Edition in English) (2013)
Dennis U Nielsen et al.
Organic letters, 13(16), 4454-4457 (2011-07-28)
A simple protocol is reported for the preparation of primary aryl amides under Pd-catalyzed carbonylation chemistry applying a two-chamber system with crystalline and nontransition metal based sources of carbon monoxide and ammonia. The method is suitable for the synthesis of
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Studies in the field of carbonylation chemistry led to the discovery of a novel carbon monoxide (CO) delivery system.

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