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745146

9-甲基-9 H-芴-9-羰基-¹³氯化氯

Name: 9-甲基-9 <I>H</I>-芴-9-羰基-<SUP>13</SUP>氯化氯
Brand: ALDRICH

≥97.0% (GC)

别名:

¹³COgen

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About This Item

经验公式（希尔记法）:

¹³CC₁₄H₁₁ClO

CAS号:

1072315-89-9

分子量:

243.69

MDL號碼:

MFCD18839249

分類程式碼代碼:

12352005

PubChem物質ID:

329764967

NACRES:

NA.22

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Slide 1 of 10

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STW1

COware gas reactor

Sigma-Aldrich

205958

碳负载铂催化剂

Sigma-Aldrich

745022

9-甲基-9H-芴-9-羰基氯

Sigma-Aldrich

205699

碳负载钯催化剂

Sigma-Aldrich

445460

HATU

Sigma-Aldrich

738565

碳负载铂钴

STW5

COware gas reactor

Sigma-Aldrich

205974

氧化铝负载铂

Sigma-Aldrich

763403

RuPhos Pd G3

Sigma-Aldrich

520624

二氧化铂水合物

同位素純度

≥97.0%

化驗

≥97.0% (GC)

形狀

solid

反應適用性

reaction type: C-C Bond Formation

SMILES 字串

CC1(c2ccccc2-c3ccccc13)[13C](Cl)=O

InChI

1S/C15H11ClO/c1-15(14(16)17)12-8-4-2-6-10(12)11-7-3-5-9-13(11)15/h2-9H,1H3/i14+1

InChI 密鑰

ZQYOOHGEBHBNTP-UJKGMGNHSA-N

應用

COGen is a simple alternative for carbon monoxide generation in the application of palladium-catalyzed carbonylation reactions. This reagent has proved to be applicable in a wide range of applications and is compatible with several building blocks in the formation of ketones, amides, esters, etc.

For more information please visit: Technology Spotlight, Professor Skrystrup PPP

Use with the COware Platform

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

聯結

Frequently Asked Questions are available for this Product.

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产品编号

说明

价格

訊號詞

Danger

危險聲明

H314

防範說明

P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

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Palladium-catalyzed carbonylative α-arylation for accessing 1,3-diketones.

Thomas M Gøgsig et al.

Angewandte Chemie (International ed. in English), 51(3), 798-801 (2011-12-06)

[¹⁴C]-Carbon Monoxide

Journal of Labelled Compounds & Radiopharmaceuticals, 55, 411-418 (2012)

Carbonylative Heck reactions using CO generated ex situ in a two-chamber system.

Philippe Hermange et al.

Organic letters, 13(9), 2444-2447 (2011-04-08)

A carbonylative Heck reaction of aryl iodides and styrene derivatives employing a two-chamber system using a stable, crystalline, and nontransition metal based carbon monoxide source is reported. By applying near-stoichiometric amounts of the carbon monoxide precursor, an effective exploitation of

Ex situ generation of stoichiometric and substoichiometric 12CO and 13CO and its efficient incorporation in palladium catalyzed aminocarbonylations.

Philippe Hermange et al.

Journal of the American Chemical Society, 133(15), 6061-6071 (2011-03-31)

A new technique for the ex situ generation of carbon monoxide (CO) and its efficient incorporation in palladium catalyzed carbonylation reactions was achieved using a simple sealed two-chamber system. The ex situ generation of CO was derived by a palladium

Palladium-catalyzed approach to primary amides using nongaseous precursors.

Dennis U Nielsen et al.

Organic letters, 13(16), 4454-4457 (2011-07-28)

A simple protocol is reported for the preparation of primary aryl amides under Pd-catalyzed carbonylation chemistry applying a two-chamber system with crystalline and nontransition metal based sources of carbon monoxide and ammonia. The method is suitable for the synthesis of

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9-甲基-9 H-芴-9-羰基-¹³氯化氯