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741248

Sigma-Aldrich

双三苯基膦二氯化钯

别名:

PdCl2(PPh3)2, 三苯基膦氯化钯, 二氯二(三苯基膦)钯(II)

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1 G
$61.40
5 G
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1 G
$61.40
5 G
$291.00
25 G
$791.00

About This Item

线性分子式:
[(C6H5)3P]2PdCl2
CAS号:
13965-03-2
分子量:
701.90
Beilstein:
4935975
EC 号:
237-744-2
MDL编号:
MFCD00009593
UNSPSC代码:
12161600
PubChem化学物质编号:
329765477
NACRES:
NA.22

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表单

solid

质量水平

100

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand

官能团

phosphine

SMILES字符串

Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4

InChI

1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2

InChI key

YNHIGQDRGKUECZ-UHFFFAOYSA-L

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应用

钯催化交叉偶联反应应用指南
二（三苯基膦）二氯化钯 (II) 通常用作通过 斯蒂尔偶联合成共轭聚合物的催化剂 。[1]它也适用于其他偶联反应，如铃木[2] 和 Sonogashira-偶联反应[3]

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象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H317,H413

危险分类

Aquatic Chronic 4 - Skin Sens. 1A

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCX6018
MKCX2497
MKCW6286
MKCT5715
MKCS4431

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New oligomeric poly (ether-imide) s containing diphenylsilane and dibenzofuran moieties. Synthesis and characterization.
Tundidor-Camba A, et al.
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 55(4), 324-331 (2018)
Synthesis of quaternized zinc (II) and cobalt (II) phthalocyanines bearing pyridine-2-yl-ethynyl groups and their DNA binding properties.
Alishah MM, et al.
Turkish Journal of Chemistry, 42(2), 572-585 (2018)
Influence of catalytic systems in Stille polymerization on the electrochromic performance of diketopyrrolopyrrole-based conjugated polymers.
Neo WT, et al.
Materials Chemistry Frontiers. (2018)
Ganesan Bharathiraja et al.
Organic & biomolecular chemistry, 13(9), 2786-2792 (2015-01-22)
Various tetrasubstituted pyrroles/pyrazoles have been prepared from nitro-substituted 1,3-enynes with aromatic amines/hydrazines via a copper-catalyzed cascade aza-Michael addition, cyclization and aromatization at room temperature. This protocol is also effective for the synthesis of tetrasubstituted pyrazoles in high yields.
Hiroaki Imoto et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(34), 12105-12111 (2015-07-17)
Aggregation-induced emission (AIE)-active maleimide dyes, namely, 2-p-toluidino-N-p-tolylmaleimide, 3-phenyl-2-toluidino-N-p-tolylmaleimide, 2-p-thiocresyl-3-p-toluidino-N-p-tolylmaleimide, and 2,3-dithiocresyl-N-arylmaleimides, were synthesized by facile synthetic procedures. The dyes show intense emission in the solid state, and emission colors were controlled from green (λmax =527 nm) to orange (λmax =609 nm) by

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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