732737

4-(苯甲醛二乙缩醛)溴化镁 溶液

1 M in THF

• 别名: 4-(Diethoxymethyl)phenylmagnesium bromide
• 经验公式（希尔记法）: C₁₁H₁₅BrMgO₂
• 分子量: 283.44
• MDL编号: MFCD11553216
• UNSPSC代码: 12352103
• PubChem化学物质编号: 329764754
• NACRES: NA.22

属性

• 表单: solution
• 反应适用性: reaction type: Grignard Reaction
• 浓度: 1 M in THF
• 密度: 1.013 g/mL at 25 °C
• 官能团: ether
• SMILES字符串: CCOC(OCC)c1ccc([Mg]Br)cc1
• InChI: 1S/C11H15O2.BrH.Mg/c1-3-12-11(13-4-2)10-8-6-5-7-9-10;;/h6-9,11H,3-4H2,1-2H3;1H;/q;;+1/p-1
• InChI key: APPJPCOJOCVSMA-UHFFFAOYSA-M

说明

应用

4-(Benzaldehyde diethylacetal)magnesium bromide can be used as a substrate in the sp³ C-H arylation of tetrahydroisoquinolines using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ).[1]

安全信息

• 象形图: GHS02,GHS08,GHS05,GHS07
• 警示用语：: Danger
• 危险声明: H225,H314,H335,H336,H351
• 预防措施声明: P202 - P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• 危险分类: Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1C - STOT SE 3
• 靶器官: Respiratory system
• 补充剂危害: EUH014,EUH019
• 储存分类代码: 3 - Flammable liquids
• WGK: WGK 3
• 闪点(°F): -22.0 °F
• 闪点(°C): -30 °C