718386

二异丁基-叔丁氧基氢化铝锂 溶液

0.25 M in THF/hexanes

• 别名: LDBBA
• 经验公式（希尔记法）: C₁₂H₂₈AlLiO
• CAS号: 77299-63-9
• 分子量: 222.27
• MDL编号: MFCD16621454
• UNSPSC代码: 12352103
• PubChem化学物质编号: 329763573
• NACRES: NA.22

属性

• 表单: liquid
• 质量水平: 100
• 反应适用性: reagent type: reductant
• 浓度: 0.25 M in THF/hexanes
• 密度: 0.795 g/mL at 25 °C
• 储存温度: 2-8°C
• SMILES字符串: [Li+].CC(C)C[AlH-](CC(C)C)OC(C)(C)C
• InChI: 1S/C4H9O.2C4H9.Al.Li.H/c1-4(2,3)5;2*1-4(2)3;;;/h1-3H3;2*4H,1H2,2-3H3;;;/q-1;;;;+1;
• InChI key: HNIYOHKCLUHKGY-UHFFFAOYSA-N

说明

应用

Lithiumdiisobutyl-tert-butoxyaluminum hydride solution can be used as a reducing agent for the reduction of:

• Aromatic and aliphatic nitriles to aldehydes.
• Aromatic and aliphatic esters to aldehydes.
• Tertiary amides to aldehydes.

安全信息

• 象形图: GHS02,GHS08,GHS07,GHS09
• 警示用语：: Danger
• 危险声明: H225,H261,H304,H315,H319,H335,H336,H351,H361f,H411
• 预防措施声明: P210 - P231 + P232 - P273 - P301 + P310 - P303 + P361 + P353 - P331
• 危险分类: Aquatic Chronic 2 - Asp. Tox. 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT SE 3 - Water-react 2
• 靶器官: Central nervous system, Respiratory system
• 补充剂危害: EUH019
• 储存分类代码: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• WGK: WGK 3