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Merck
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文件

71290

Sigma-Aldrich

叠氮化钠

purum p.a., ≥99.0% (T)

别名:

Hydrazoic acid sodium salt, NSC 3072

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About This Item

线性分子式:
NaN3
CAS号:
26628-22-8
分子量:
65.01
EC號碼:
247-852-1
MDL號碼:
MFCD00003536
分類程式碼代碼:
12352201
PubChem物質ID:
57652281
NACRES:
NA.21

等級

purum p.a.

化驗

≥99.0% (T)

形狀

crystals

溶解度

H2O: 0.1 g/mL, clear, colorless

負離子痕跡

chloride (Cl-): ≤50 mg/kg
sulfate (SO42-): ≤50 mg/kg

正離子痕跡

Ca: ≤50 mg/kg
Cd: ≤50 mg/kg
Co: ≤50 mg/kg
Cu: ≤50 mg/kg
Fe: ≤50 mg/kg
K: ≤100 mg/kg
Ni: ≤50 mg/kg
Pb: ≤50 mg/kg
Zn: ≤50 mg/kg

SMILES 字串

[Na]N=[N+]=[N-]

InChI

1S/N3.Na/c1-3-2;/q-1;+1

InChI 密鑰

PXIPVTKHYLBLMZ-UHFFFAOYSA-N

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相关类别

應用

Catalyst for:
  • Oxidative decarboxylation
  • Michael addition reactions

Reagent for synthesis of
  • Blue fluorescent copolymers
  • Metal phosphonates
  • Arenes via aminations

Involved in regioselective synthesis of prianosin B

其他說明

与醛和羧酸的 Schmidt 反应，综述

建議使用防濺手套

产品编号
说明
价格

訊號詞

Danger

危險分類

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2 Oral

標靶器官

Brain

安全危害

EUH032

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 2

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

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G.I. Koldobski et al.
Russ. Chem. Rev., 47, 1084-1084 (1978)
H. Chen, et al.,
Macromolecules, 43, 3613-3623 (2010)
Y. Wada, et al.,
Tetrahedron, 65, 1059-1062 (2009)
Xiaohua Sun et al.
Organic letters, 9(22), 4495-4498 (2007-10-04)
A novel intermolecular cross-double-Michael addition between nitro and carbonyl activated olefins has been developed through Lewis base catalysis. The reaction took place with a large group of beta-alkyl nitroalkenes and alpha,beta-unsaturated ketone/esters, producing an allylic nitro compound in good to
Deng-Ke Cao et al.
Inorganic chemistry, 44(10), 3599-3604 (2005-05-10)
Based on the [hydroxy(4-pyridyl)methyl]phosphonate ligand, three compounds with formula Ni{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (1), Cd{(4-C(5)H(4)N)CH(OH)PO(3)}(H(2)O) (2), and Gd{(4-C(5)H(4)N)CH(OH)P(OH)O(2)}(3).6H(2)O (3) have been synthesized under hydrothermal conditions. The crystal data for 1 are as follows: orthorhombic, space group Pbca, a = 8.7980(13) A, b =
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