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703907

Sigma-Aldrich

RuCl(p-异丙基甲苯)[(R,R)-Ts-DPEN]

别名:

[N-[(1R,2R)-2-(氨基-κN)-1,2-二苯基乙基]-4-甲基苯磺酰胺合-κN]氯[(1,2,3,4,5,6-η)-1-甲基-4-(1-甲基乙基)苯]-钌

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About This Item

经验公式（希尔记法）:
C31H35ClN2O2RuS
CAS号:
192139-92-7
分子量:
636.21
MDL编号:
MFCD10567385
UNSPSC代码:
12352116
PubChem化学物质编号:
329762075
NACRES:
NA.22

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表单

powder

质量水平

100

旋光性

[α]20/D −116°, c = 0.1 in chloroform

mp

215 °C

官能团

amine
phenyl

储存温度

2-8°C

SMILES字符串

CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@@H]([C@H](N)c3ccccc3)c4ccccc4

InChI

1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1

InChI key

AZFNGPAYDKGCRB-AGEKDOICSA-M

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相关类别

一般描述

RuCl（对伞花烃）[（R,R）-Ts-DPEN]是一种与钌络合的手性二胺配体。[1]

应用

用于不对称反应的 Takasago 配体和配合物
用于对映选择性加氢的膦阳离子钌催化剂：
  • 喹啉
  • N-烷基酮亚胺
  • 从细菌中分离的天然产物的抗肿瘤和抗增殖衍生物
  • 羟基芳醛通过 Rap-Stoermer-对映选择性转移氢化

通过纳米笼的微环境工程改进的性能改进的催化剂

法律信息

与 Takasago 合作销售，仅用于研究目的。WO9720789

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCS8197
MKCM4557
MKCL9456
MKCJ9480
MKCG8576

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Carbonyl compounds: still central to organic synthesis
Aldrichimica Acta, 41(4) (2008)

商品

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

相关内容

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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