跳转至内容
Merck

698121

Sigma-Aldrich

4-碘苯硼酸 MIDA 酯

97%

别名:

2-(4-碘苯基)-6-甲基-1,3,6,2-二氧氮杂硼烷-4,8-二酮

登录查看公司和协议定价


About This Item

经验公式(希尔记法):
C11H11BINO4
分子量:
358.92
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.22
如需咨询该产品698121,请联系默克当地办事处或经销商。 联系技术服务部门

方案

97%

表单

solid

mp

213-217 °C

SMILES字符串

CN1CC(=O)OB(OC(=O)C1)c2ccc(I)cc2

InChI

1S/C11H11BINO4/c1-14-6-10(15)17-12(18-11(16)7-14)8-2-4-9(13)5-3-8/h2-5H,6-7H2,1H3

InChI key

KIKNJEGAWBNFLW-UHFFFAOYSA-N

应用

4-Iodophenylboronic acid MIDA ester can be used:
  • As a starting material to prepare rod-like hydrogen-bonded organic frameworks through Stille-coupling using 2,5-bis(trimethyltin)heterocycle, Pd(PPh3)4, and CuI.[1]
  • As a substrate in the C-H arylation reaction of pyroglutamic acid derivatives with aryl and heteroaryl iodides; catalyzed by the palladium catalyst.[2]
  • As a substrate in the synthesis of trifluoroborates, which are further converted to protected boronic acids.[3]
  • As a starting material in the synthesis of amino acid MIDA boronates as new building blocks by reacting with protected iodoalanine.[4]

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Acute Tox. 4 Oral

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

没有发现合适的版本?

如果您需要特殊版本,可通过批号或批次号查找具体证书。

已有该产品?

在文件库中查找您最近购买产品的文档。

访问文档库

Stereospecific palladium-catalyzed C-H arylation of pyroglutamic acid derivatives at the C3 position enabled by 8-aminoquinoline as a directing group
Verho O, et al.
Organic Letters, 19(17), 4424-4427 (2017)
A general method for interconversion of boronic acid protecting groups: Trifluoroborates as common intermediates
Churches QI, et al.
The Journal of Organic Chemistry, 80(11), 5428-5435 (2015)
Permanently porous hydrogen-bonded frameworks of rod-like thiophenes, selenophenes, and tellurophenes capped with MIDA boronates
Li P, et al.
Dalton Transactions, 45(24), 9754-9757 (2016)
Synthesis and properties of MIDA boronate containing aromatic amino acids: New peptide building blocks
Colgin N, et al.
Organic & Biomolecular Chemistry, 9(6), 1864-1870 (2011)

Questions

Reviews

No rating value

Active Filters

我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门