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Merck
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文件

688487

Sigma-Aldrich

2-均三甲苯基-2,5,6,7-四氢吡咯并[2,1-c][1,2,4]三唑-4-鎓氯化物

97%

别名:

Bode 催化剂 3

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About This Item

经验公式（希尔记法）:
C14H18ClN3
CAS号:
862893-81-0
分子量:
263.77
分類程式碼代碼:
12352005
PubChem物質ID:
329761167
NACRES:
NA.22

化驗

97%

形狀

solid

反應適用性

reagent type: catalyst

mp

200-205 °C

SMILES 字串

[Cl-].Cc1cc(C)c(c(C)c1)-[n+]2cn3CCCc3n2

InChI

1S/C14H18N3.ClH/c1-10-7-11(2)14(12(3)8-10)17-9-16-6-4-5-13(16)15-17;/h7-9H,4-6H2,1-3H3;1H/q+1;/p-1

InChI 密鑰

KKBONGWVMVUYPA-UHFFFAOYSA-M

相关类别

應用

Catalyst for:
  • Intermolecular hydroacylation of cyclopropenes
  • Crossed acyloin condensations
  • Domino ring-opening redox amidation Knoevenagel condensation
  • Claisen rearrangement
  • Lewis acid- and N-heterocyclic carbene-catalyzed cyclocondensation reaction
  • Bode catalyst for enantioselective cyclizations

法律資訊

与 BioBlock, Inc. 联合销售

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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N-Heterocyclic Carbene (NHC) Compounds

Rovis has demonstrated that triazolium salt in the presence of a base can act as an N-heterocyclic carbene organocatalyst1 in highly enantioselective intramolecular Stetter reactions.

Knoevenagel Condensation Reaction

Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.

相关内容

N-Heterocyclic Carbene (NHC) Compounds

Rovis has demonstrated that triazolium salt in the presence of a base can act as an N-heterocyclic carbene organocatalyst1 in highly enantioselective intramolecular Stetter reactions.

Bode Group – Professor Product Portal

The Bode Group aims to develop new reactions and reagents for the synthesis of complex molecules. The Bode Group has developed N-mesityl-substituted NHCs as organocatalysts for the catalytic generation of reactive species including activated carboxylates, homoenolates, and enolates. These novel catalysts and reactions have made possible a new generation of highly enantioselective annulations from simple starting materials under mild reaction conditions, usually at room temperature and without added reagents. Furthering the goal of designing new reagents to enable the assembly of complex molecules, the Bode group has developed SnAP reagents for the facile, one-pot conversion of aldehydes into N-unprotected, saturated N-heterocycles, including bicyclic and spirocyclic structures. These easy to handle reagents provide a simple and robust alternative to the challenging and restrictive cross-coupling methods for the functionalization of saturated N-heterocycles.

Knoevenagel Condensation Reaction

Knoevenagel Condensation is an organic reaction named after Emil Knoevenagel. It is a classic C-C bond formation reaction and a modification of the Aldol Condensation.

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