656577

1,3-二异丙基咪唑氯

97%

• 别名: N,N′-(异丙基)氯化咪唑鎓
• 经验公式（希尔记法）: C₉H₁₇ClN₂
• CAS号: 139143-09-2
• 分子量: 188.70
• MDL编号: MFCD03840577
• UNSPSC代码: 12352005
• PubChem化学物质编号: 24884209
• NACRES: NA.22

属性

• 质量水平: 200
• 方案: 97%
• 表单: solid
• 反应适用性: reagent type: catalyst
• 环保替代产品特性: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 182-186 °C
• 环保替代产品分类: Aligned,
• SMILES字符串: [Cl-].CC(C)n1cc[n+](c1)C(C)C
• InChI: 1S/C9H17N2.ClH/c1-8(2)10-5-6-11(7-10)9(3)4;/h5-9H,1-4H3;1H/q+1;/p-1
• InChI key: DOFXKPAOJLLPII-UHFFFAOYSA-M

说明

一般描述

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

应用

1,3-Diisopropylimidazolium chloride may be used to prepare:

• 1,3-Diisopropylimidazole-2-thione by reacting with sulfur in the presence of potassium carbonate.[1]
• (C₉H₇)NiCl(1,3-diisopropylimidazol-2- ylidene) by reacting with bis-indenyl nickel-(II).[2]
• Ruthenium N-heterocyclic carbene complexes, which are efficient catalysts for the amidation of primary alcohols and amines.[3][4]

Ligand for ruthenium-catalyzed greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Amide Synthesis from Alcohols and Amines by the Extrusion of Dihydrogen

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves