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About This Item
线性分子式:
InCl3 · aq
CAS号:
分子量:
221.18 (anhydrous basis)
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.22
推荐产品
反應適用性
core: indium
reagent type: catalyst
濃度
~39% In
雜質
2-3 mol/mol water
SMILES 字串
O.Cl[In](Cl)Cl
InChI
1S/3ClH.In.H2O/h3*1H;;1H2/q;;;+3;/p-3
InChI 密鑰
KYCHGXYBBUEKJK-UHFFFAOYSA-K
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應用
Reagent/catalyst for various organic transformations, e.g. allylation of aldehydes, ketones, and quinones; Diels-Alder reaction; the aldol reaction; Michael additions; the reductive Friedel-Crafts;
訊號詞
Danger
危險聲明
危險分類
Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation
標靶器官
Lungs
儲存類別代碼
6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Chapman, C. J.; Frost, C. G. et al.
Tetrahedron Letters, 42, 773-773 (2001)
S Kobayashi et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 6(19), 3491-3494 (2000-11-10)
Group 3-15 metal chlorides (Lewis acids) were classified on the basis of activity and aldehyde- and aldimine-selectivity in an addition reaction of a silyl enol ether. Based on the experimental results, metal chlorides (Lewis acids) were classified as follows: A
Reddy, B. G.; Kumareswaran, R. et al.
Tetrahedron Letters, 41, 10333-10333 (2000)
Loh, T.-P.; Li, X.-R.,
Angewandte Chemie (International Edition in English), 36, 980-980 (1997)
InCl3-driven regioselective synthesis of functionalized/annulated quinolines: scope and limitations.
Tanmoy Chanda et al.
Chemistry, an Asian journal, 7(4), 778-787 (2012-02-09)
The efficient, regioselective synthesis of functionalized/annulated quinolines was achieved by the coupling of 2-aminoaryl ketones with alkynes/active methylenes/α-oxoketene dithioacetals promoted by InCl(3) in refluxing acetonitrile as well as under solvent-free conditions in excellent yields. This transformation presumably proceeded through the
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