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Merck

203440

Sigma-Aldrich

三氯化铟

99.999% trace metals basis

别名:

三氯化铟

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1 G
$124.00
10 G
$322.00
50 G
$1,520.00

About This Item

线性分子式:
InCl3
CAS号:
分子量:
221.18
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

$124.00


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质量水平

方案

99.999% trace metals basis

表单

powder or flakes (or chunks)

反应适用性

reagent type: catalyst
core: indium

杂质

≤15.0 ppm Trace Metal Analysis

密度

3.46 g/mL at 25 °C (lit.)

SMILES字符串

Cl[In](Cl)Cl

InChI

1S/3ClH.In/h3*1H;/q;;;+3/p-3

InChI key

PSCMQHVBLHHWTO-UHFFFAOYSA-K

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一般描述

氯化铟是一种路易斯酸催化剂,适于多种有机反应。还用于催化、太阳能电池和光电领域。[1][2]

应用

氯化铟适于:
  • 作为醛和酮制备1,3-二硫戊环的催化剂。 [1]
  • 用于酚、硫醇、醇和胺的酰化。 [3]
  • 作为前体制备染料敏化太阳能电池的氧化铟锡(ITO)薄膜。 [2]
  • 制备溶液加工的 氧化物半导体薄膜晶体管(OS TFT)用于 显示装置。[4]

象形图

Health hazardCorrosion

警示用语:

Danger

危险声明

危险分类

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1C - STOT RE 1 Inhalation

靶器官

Lungs

储存分类代码

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis, 1712-1712 (2007)
Mecheril Valsan Nandakumar et al.
Chemical communications (Cambridge, England), (26), 2756-2758 (2007-06-28)
The indium-bipyridine-catalyzed, enantioselective ring-opening of meso-epoxides with aliphatic and aromatic thiols furnished 1,2-mercapto alcohols in good yields and excellent enantioselectivities; the crystal structure of the chiral catalyst reveals a pentagonal-bipyramidal coordination geometry around the indium center.
Indium(III) chloride as an efficient, convenient catalyst for thioacetalization and its chemoselectivity
Sengodagounder Muthusamy, et al.
Tetrahedron Letters, 42, 359-362 (2001)
Tetrahedron Letters, 48, 6743-6743 (2007)
A systematic study on effects of precursors and solvents for optimization of solution-processed oxide semiconductor thin-film transistors
Keon-Hee Lim, et al.
Journal of Materials Chemistry, 5, 7768-7776 (2017)

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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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