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Merck
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557749

Sigma-Aldrich

N-Boc-5-溴吲哚

97%

别名:

5-溴吲哚-1-羧酸叔丁酯

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About This Item

经验公式（希尔记法）:
C13H14BrNO2
CAS号:
182344-70-3
分子量:
296.16
MDL编号:
MFCD02090067
UNSPSC代码:
12352100
PubChem化学物质编号:
24879694
NACRES:
NA.22

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质量水平

100

方案

97%

表单

solid

mp

56-57 °C (lit.)

官能团

bromo

SMILES字符串

CC(C)(C)OC(=O)n1ccc2cc(Br)ccc12

InChI

1S/C13H14BrNO2/c1-13(2,3)17-12(16)15-7-6-9-8-10(14)4-5-11(9)15/h4-8H,1-3H3

InChI key

PBWDRTGTQIXVBR-UHFFFAOYSA-N

相关类别

一般描述

N-Boc-5-bromoindole can undergo Sonogashira coupling reaction with N,N-diisopropylprop-2-ynylamine to afford the corresponding propargylic diisopropylamine.[1] N-Boc-5-bromoindole is formed as an intermediate during the synthesis of 2-(5-substituted-1H-indol-3-yl)-N-hydroxyacetamide derivatives.[2]

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBD7688V
13796BM
22497HJ
76096DJ
02526JH

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Sylvain Petit et al.
ChemMedChem, 4(2), 261-275 (2008-12-05)
The lead compound 5-bromoindolyl-3-acetohydroxamic acid (10) was recently identified as a potent inhibitor of bacterial peptide deformylases (PDFs). The synthesis and associated activities of new variants were investigated at position 5 to optimize the fit at the S1' subsite and
Hiroyuki Nakamura et al.
The Journal of organic chemistry, 70(6), 2357-2360 (2005-03-12)
[reaction: see text] Propargylic diisopropylamines containing heterocycles, which were prepared readily from heterocyclic bromides and propargyldiisopropylamine by the Sonogashira coupling reaction, underwent the allene transformation reaction in the presence of Pd(2)(dba)(3).CHCl(3) catalyst (2.5 mol %) and 1,2-bis[bis(pentafluorophenyl)phosphino]ethane (10 mol %)

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