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Merck
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文件

524336

Sigma-Aldrich

4-溴吲哚

96%

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About This Item

经验公式（希尔记法）:
C8H6BrN
CAS号:
52488-36-5
分子量:
196.04
MDL號碼:
MFCD00671502
分類程式碼代碼:
12352100
PubChem物質ID:
24874403
NACRES:
NA.22

化驗

96%

折射率

n20/D 1.655 (lit.)

bp

283-285 °C (lit.)

密度

1.563 g/mL at 25 °C (lit.)

SMILES 字串

Brc1cccc2[nH]ccc12

InChI

1S/C8H6BrN/c9-7-2-1-3-8-6(7)4-5-10-8/h1-5,10H

InChI 密鑰

GRJZJFUBQYULKL-UHFFFAOYSA-N

相关类别

應用

4-溴吲哚可用于合成：
  • clavicipitic acid，一种麦角生物碱
  • 4-溴氢色氨酸
  • 3-吲哚基乙腈衍生物
  • 海生生物碱双氰菊酯 B

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

230.0 °F - closed cup

閃點（°C）

110 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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S Liras et al.
Journal of the American Chemical Society, 123(25), 5918-5924 (2001-06-21)
Concise syntheses of the Ergot alkaloids rugulovasine A (3a), rugulovasine B (3b), and setoclavine (2) have been completed by strategies that feature inter- and intramolecular vinylogous Mannich reactions as the key steps. Thus, the first synthesis of 3a,b commenced with
Metal-halogen exchange of bromoindoles. A route to substituted indoles.
Moyer MP, et al.
The Journal of Organic Chemistry, 51(26), 5106- 5110 (1986)
Optically active total synthesis of clavicipitic acid.
Yokoyama Y, et al.
The Journal of Organic Chemistry, 60(6), 1486-1487 (1995)
Andrew K Pitts et al.
Angewandte Chemie (International ed. in English), 54(18), 5451-5455 (2015-02-24)
A sequential CH functionalization strategy for the synthesis of the marine alkaloid dictyodendrin B is reported. Our synthesis begins from commercially available 4-bromoindole and involves six direct functionalizations around the heteroarene core as part of a gram-scale strategy towards the natural
Chaitany Jayprakash Raorane et al.
Biomolecules, 10(8) (2020-08-23)
Multi-drug resistant Acinetobacter baumannii is well-known for its rapid acclimatization in hospital environments. The ability of the bacterium to endure desiccation and starvation on dry surfaces for up to a month results in outbreaks of health care-associated infections. Previously, indole

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