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Merck
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543101

Sigma-Aldrich

乙酸 5-己烯酯

97%

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About This Item

线性分子式:
CH3CO2(CH2)4CH=CH2
CAS号:
5048-26-0
分子量:
142.20
MDL编号:
MFCD00060856
UNSPSC代码:
12352100
PubChem化学物质编号:
24878662
NACRES:
NA.22

方案

97%

折射率

n20/D 1.423 (lit.)

沸点

173-174 °C (lit.)

密度

0.883 g/mL at 25 °C (lit.)

SMILES字符串

CC(=O)OCCCCC=C

InChI

1S/C8H14O2/c1-3-4-5-6-7-10-8(2)9/h3H,1,4-7H2,2H3

InChI key

MPLWNENKBSBMFN-UHFFFAOYSA-N

一般描述

5-Hexenyl acetate is a linear ester. It can undergo ruthenium-catalyzed cross-metathesis reactions with α-substituted vinyl boronates in dichloromethane.[1] It participates in the post-polymerization modification step during the preparation of poly(vinylnorbornene).[2]

应用

5-Hexenyl acetate may be used in the synthesis of (4E,7Z)-4,7-tridecadienyl acetate.[3]

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

141.1 °F - closed cup

闪点(°C)

60.6 °C - closed cup

个人防护装备

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCP2230
MKBT1716V
MKBK3952V
01110JJ
09020JD

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Xicotencatl Camacho-Coronel et al.
Frontiers in plant science, 11, 121-121 (2020-03-12)
Numerous plant-derived volatile organic compounds (VOCs) induce the expression of resistance-related genes and thereby cause an "associational resistance" in neighbouring plants. However, VOCs can also be sequestered by plant cuticular waxes. In case that they maintain their biological activity, such
Nonconjugated dienes from 1-alkenes: Application to the synthesis of sex pheromone (4E, 7Z)-4, 7-Tridecadienyl acetate
Kim TH and Park KM
Tetrahedron Letters, 36.27, 4833-4836 (1995)
Ring-opening metathesis polymerization of vinylnorbornene and following polymer modifications
Balcar H, et al.
Journal of Polymer Research, 21.9, 1-8 null
Synthesis of tri-substituted vinyl boronates via ruthenium-catalyzed olefin cross-metathesis
Morrill C, et al.
Tetrahedron Letters, 45.41 , 7733-7736 (2004)
Xuejiao Gao et al.
Nature communications, 9(1), 118-118 (2018-01-11)
It is known that self-assembled molecular monolayer doping technique has the advantages of forming ultra-shallow junctions and introducing minimal defects in semiconductors. In this paper, we report however the formation of carbon-related defects in the molecular monolayer-doped silicon as detected
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