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质量水平
方案
98%
mp
73-76 °C (lit.)
官能团
amine
chloro
oxime
SMILES字符串
O\N=C\c1ccccc1Cl
InChI
1S/C7H6ClNO/c8-7-4-2-1-3-6(7)5-9-10/h1-5,10H/b9-5+
InChI key
FZIVKDWRLLMSEJ-WEVVVXLNSA-N
一般描述
2-Chlorobenzaldehyde oxime is also known as o-chlorobenzaldehyde oxime. It can be synthesized by reacting 2-chlorobenzaldehyde and hydroxylamine hydrochloride.[1]
应用
2-Chlorobenzaldehyde oxime may be used in the preparation of:
- 2-chlorobenzaldehyde under different reaction conditions[2][3][4][5]
- methyl 3-(2-chlorophenyl)-5-[1-(4-methoxybenzyloxy)-ethyl]isoxazole-4-carboxylate[6]
- dimethyl 3-(2-chlorophenyl)isoxazole-4,5-dicarboxylate[1]
- [3-(2-chlorophenyl)isoxazol-5-yl]methanol[7]
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Solid-phase synthesis of 5-isoxazol-4-yl-[1,2,4] oxadiazoles.
Quan C and Kurth M.
The Journal of Organic Chemistry, 69(5), 1470-1474 (2004)
Hypervalent iodine mediated synthesis of di-and tri-substituted isoxazoles via [3+2] cycloaddition of nitrile oxides.
Singhal A, et al.
Tetrahedron, 57(7), 719-722 (2016)
Microwave-assisted chemoselective cleavage of oximes to their corresponding carbonyl compounds using 1, 3-dichloro-5, 5-dimethyl-hydantoin (DCDMH) as a new Deoximating reagent.
Khazaei A and Manesh AA.
Synthesis, 2005(12), 1929-1931 (2005)
A mild and selective method for the conversion of oximes into ketones and aldehydes by the use of N-bromophthalimide.
Khazaei A, et al.
J. Chem. Res. (M), 2004(10), 695-696 (2004)
Facile and Chemoselective Microwave-Assisted Cleavage of Oximes to Their Corresponding Carbonyl Compounds Using N,N?-Dibromo-N,N?-1,3-propylene-bis[(4-methylphenyl)sulfonamide] as a Deoximating Reagent.
Khazaei A, et al.
Synthesis, 2004(17), 2784-2786 (2004)
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