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质量水平
方案
97%
mp
82-85 °C (lit.)
官能团
aldehyde
fluoro
SMILES字符串
Oc1ccc(F)cc1C=O
InChI
1S/C7H5FO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H
InChI key
FDUBQNUDZOGOFE-UHFFFAOYSA-N
一般描述
5-Fluorosalicylaldehyde can be synthesized from 4-fluorophenol.[1]
应用
5-Fluorosalicylaldehyde may be used to synthesize:
- managanese (III) complex [MnLa(μ1,3-N3)]n [H2La = N,N′-bis(5-fluorosalicylidene)-1,2-diaminoethane][2]
- enantiopure 4-amino-6-fluoro-3-(hydroxymethyl)chromanes[3]
- 4,4′-difluoro-2,2′-[(hydrazine-1,2-diylidene)bis(methanylylidene)]-diphenol[4]
- N,N′-bis(5-fluoro-2-hydroxybenzylidene)ethylenediamine[4]
- N,N′-(2-hydroxypropane-1,3-diyl)-bis(salicylaldimine (H2L)[5]
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
其他客户在看
Large perturbations of long-range n J (1H, 1H) and n J (1H, 19F) by the intramolecular hydrogen bonds in 2-mercaptobenzaldehyde, salicylaldehyde, and some derivatives. Reference structures for intramolecular hydrogen bonds.
Schaefer T, et al.
Canadian Journal of Chemistry, 71(7), 960-967 (1993)
Synthesis, Characterization and Crystal Structures of N, N'-bis (5-Fluoro-2-hydroxybenzylidene)-ethylenediamine and 4, 4'-Difluoro-2, 2'-[(hydrazine-1, 2-diylidene) bis (methanylylidene)] diphenol.
Zhang WM, et al.
Asian Journal of Chemistry, 26(22), 7843-7843 (2014)
Synthesis and crystal structure of a novel tri-nuclear nickel (II) complex derived from N, N'-(2-hydroxypropane-1, 3-diyl) bis (salicylaldimine).
Cui YM, et al.
Russian Journal of Coordination Chemistry, 40(10), 768-772 (2014)
Manganese (III) complexes derived from bis-Schiff bases: Synthesis, structures, and antimicrobial activity.
Liu QR, et al.
Russian Journal of Coordination Chemistry, 40(10), 757-763 (2014)
Synthesis of Enantiopure 4-Amino-6-fluoro-3-(hydroxymethyl) chromanes via Intramolecular Nitrone Cycloadditions.
Broggini G, et al.
J. Chem. Res. Synop., 2, 36-37 (1997)
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