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About This Item
线性分子式:
H2C=CH(CH2)3CN
CAS号:
分子量:
95.14
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
95%
折射率
n20/D 1.427 (lit.)
沸点
165 °C (lit.)
密度
0.837 g/mL at 25 °C (lit.)
SMILES字符串
C=CCCCC#N
InChI
1S/C6H9N/c1-2-3-4-5-6-7/h2H,1,3-5H2
InChI key
UNAQSRLBVVDYGP-UHFFFAOYSA-N
一般描述
5-Hexenenitrile, an aliphatic nitrile, is a volatile compound that is formed as a degradation product of glucobrassicanapin in Aurinia sinuata.[1] It is reported to be an attractant from oilseed rape for the cabbage seed weevil, Ceutorhynchus assimilis.[2] 5-Hexenenitrile is the main volatile compound found in wheat extract.[3] It undergoes Wacker oxidation to form the corresponding methyl ketone using PdCl2-DMA (palladium dichloride-N,N-diemthylacetamide) catalytic system.[4]
应用
5-Hexenenitrile may be used in the synthesis of 1,8-dicyano-4-octene.[5]
警示用语：
Warning
危险声明
危险分类
Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
104.9 °F - closed cup
闪点(°C)
40.5 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Composition of the young green barley and wheat leaves.
Shibamoto T, et al.
J. Essent. Oil Res., 19(2), 134-137 (2007)
Convenient and Efficient Pd-Catalyzed Regioselective Oxyfunctionalization of Terminal Olefins by Using Molecular Oxygen as Sole Reoxidant.
Mitsudome T, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 118(3), 495-499 (2006)
Shengxiang Ji et al.
Polymer, 49(24), 5307-5313 (2009-11-13)
High molecular weight, high functionality diamino telechelic polybutadienes (TPBs) were synthesized by ring-opening metathesis polymerization (ROMP) of 1,5-cyclooctadiene (COD) in the presence of a chain transfer agent, 1,8-dicyano-4-octene, followed by lithium aluminum hydride reduction. Melt coupling of diamino TPB with
The responses of the cabbage seed weevil Ceutorhynchus assimilis to volatile compounds from oilseed rape in a linear track olfactometer.
Bartlet E, et al.
Entomologia Experimentalis et Applicata, 85(3), 257-262 (1997)
Glucosinolates, glycosidically bound volatiles and antimicrobial activity of Aurinia sinuata (Brassicaceae).
Blazevic I, et al.
Food Chemistry, 121(4), 1020-1028 (2010)
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