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Merck

50790

Sigma-Aldrich

氯化金 (III) 水合物

~50% Au basis

别名:

四氯金酸, 四氯金酸氢 水合物, 氯化金, 氯金酸

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250 MG
$127.00
1 G
$387.00
5 G
$1,570.00

$127.00


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250 MG
$127.00
1 G
$387.00
5 G
$1,570.00

About This Item

线性分子式:
HAuCl4 · aq
CAS号:
分子量:
339.79 (anhydrous basis)
EC 号:
MDL编号:
UNSPSC代码:
12352302
PubChem化学物质编号:
NACRES:
NA.23

$127.00


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等级

for analytical purposes

质量水平

表单

powder or crystals

浓度

~50% Au

颜色

yellow

密度

3.9 g/mL at 25 °C

SMILES字符串

O.Cl.Cl[Au](Cl)Cl

InChI

1S/Au.4ClH.H2O/h;4*1H;1H2/q+3;;;;;/p-3

InChI key

OVJUDSKPNIBLOO-UHFFFAOYSA-K

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一般描述

氯化金(III)水合物,又称氯金酸,是合成金纳米颗粒的前体。它还具有很高的催化活性。

应用

用作以下反应的催化剂:不对称醇醛缩合反应,乙烯基芳烃二硼化反应,三烷基锡烷脱氢二聚化反应,烯烃和胺羰基化反应,C-C、C-O键偶联反应、硫化物氧化反应,硫醚选择性氧化反应。[1][2]

警示用语:

Danger

危险分类

Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - STOT RE 2 Oral

靶器官

Kidney

储存分类代码

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The crystal structure of gold (III) chloride
Acta Crystallographica, 11(4), 248-288 (1958)
Raquel Casado et al.
Journal of the American Chemical Society, 125(39), 11925-11935 (2003-09-25)
Different inorganic and organometallic gold(III) and gold(I) complexes have been tested in the addition of water and methanol to terminal alkynes. Anionic and neutral organometallic gold(III) compounds can efficiently mediate these reactions in neutral media in refluxing methanol. The compounds

商品

Plasmonic nanoparticles have unique optical properties that can be tailored to suit a variety of applications in the biotechnology1–8 and electronics9–16 industries.

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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