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496383

Sigma-Aldrich

1,10-菲咯啉-5,6-二酮

97%

别名:

Stahl phd 氧化剂, phd

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1 G
$313.00

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1 G
$313.00

About This Item

经验公式（希尔记法）:
C12H6N2O2
CAS号:
27318-90-7
分子量:
210.19
MDL编号:
MFCD00014473
UNSPSC代码:
12352100
PubChem化学物质编号:
24873053
NACRES:
NA.22

$313.00

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质量水平

200

方案

97%

mp

260 °C (dec.) (lit.)

官能团

ketone

SMILES字符串

O=C1C(=O)c2cccnc2-c3ncccc13

InChI

1S/C12H6N2O2/c15-11-7-3-1-5-13-9(7)10-8(12(11)16)4-2-6-14-10/h1-6H

InChI key

KCALAFIVPCAXJI-UHFFFAOYSA-N

相关类别

一般描述

1,10-菲咯啉-5,6-二酮 (phendio) 形式的 Cu (II) 和 Ag (I) phendio 复合物，显示出有效的抗真菌和抗癌活性。[1]转换金属苯二酚配合物对玻碳电极进行修饰，使 NADH 在低过电位下发生催化氧化。[2]

应用

1,10-菲咯啉-5,6-二酮可用于与早期转换金属离子的均金属和杂金属配合物的制备。[3]
一种双官能团醌氧化剂，当与 Zn 2 + 催化剂联合使用时，可用于影响仲胺向各种增值基序（包括吲哚）的有氧氧化。

双官能团醌催化剂用于仲胺和氮杂环的生物吸入有氧氧化

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315,H319,H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
WXBF1497V
WXBF0256V
WXBD9305V
WXBD7386V
WXBD6033V

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Xuyan Mao et al.
The Analyst, 136(2), 293-298 (2010-10-20)
To improve the electrocatalytic activities of carbon nanotubes (CNT) towards the oxidation of nicotinamide adenine dinucleotide (NADH), we derive them with a redox mediator, 1,10-phenanthroline-5,6-dione (PD), by the noncovalent functionalization method. The redox carbon nanotubes (PD/CNT/GC) show excellent electrocatalytic activities
Tetsuaki Fujihara et al.
Dalton transactions (Cambridge, England : 2003), (4)(4), 645-652 (2004-07-15)
Syntheses and pH dependent electrochemical properties of aqua-ruthenium(II) complexes, [Ru(trpy)(PDA-N,N')(OH2)](ClO4)2 ([1](ClO4)2) and [Ru(trpy)(PD-N,N')(OH2)](ClO4)2 ([2](ClO4)2) (trpy = 2,2':6',2''-terpyridine, PDA = 6-acetonyl-6-hydroxy-1,10-phenanthroline-5-one, PD = 1,10-phenanthroline-5,6-dione) are presented. Treatment of [Ru(trpy)(PD-N,N')Cl](PF6) with AgClO4 in a mixed solvent of acetone and H2O selectively produced
Sudeshna Roy et al.
ChemMedChem, 3(9), 1427-1434 (2008-06-10)
Phenanthroline derivatives are of interest due to their potential activity against cancer, and viral, bacterial, and fungal infections. In a search for highly specific antitumor and antibacterial compounds, we report the activities of 1,10-phenanthroline-5,6-dione (phendione or L(1)), dipyrido[3,2-a:2',3'-c]phenazine (dppz or
Aleksandra Pinczewska et al.
Journal of the American Chemical Society, 134(43), 18022-18033 (2012-10-11)
We report the combinatorial preparation and high-throughput screening of a library of modified electrodes designed to catalyze the oxidation of NADH. Sixty glassy carbon electrodes were covalently modified with ruthenium(II) or zinc(II) complexes bearing the redox active 1,10-phenanthroline-5,6-dione (phendione) ligand
Yu-Min Song et al.
Journal of inorganic biochemistry, 103(3), 396-400 (2009-01-13)
Three new solid complexes have been synthesized by the reaction of rare earth(III) nitrate with the first ligand curcumin (HL) and the second ligand 1,10-phenanthroline-5,6-dione (L') in alcohol solution (pH=6.5-7.0). The composition of the complexes has been characterized by elemental
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Stahl Group – Professor Product Portal

he Stahl Lab focuses on the development of catalysts and catalytic reactions for selective oxidation of organic molecules, with particular emphasis on aerobic oxidation reactions.

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