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490407

Sigma-Aldrich

一氯五甲基二硅烷

97%

别名:

1-Chloro-1,1,2,2,2-pentamethyldisilane, Chlorodimethyl(trimethylsilyl)silane, Chloropentamethyldisilane, Pentamethylchlorodisilane

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About This Item

线性分子式:
(CH3)3SiSi(CH3)2Cl
CAS号:
1560-28-7
分子量:
166.80
EC 号:
216-330-5
MDL编号:
MFCD00456692
UNSPSC代码:
12352300
PubChem化学物质编号:
24872557
NACRES:
NA.23

方案

97%

表单

liquid

折射率

n20/D 1.4415 (lit.)

沸点

134-136 °C (lit.)

密度

0.862 g/mL at 25 °C (lit.)

SMILES字符串

C[Si](C)(C)[Si](C)(C)Cl

InChI

1S/C5H15ClSi2/c1-7(2,3)8(4,5)6/h1-5H3

InChI key

GJCAUTWJWBFMFU-UHFFFAOYSA-N

应用

Chloropentamethyldisilane may be used as one of the constituents for the sythesis of silyloxyjulolidine (SiN1) as a source of silyl radicals which may be used as photoinitiators for free radical photopolymerization.[1] It may also be used in the preparation of 2-pentamethyldisilanyloxymethyl)phenylpentamethyldisilane.[2]

象形图

FlameCorrosion
GHS02,GHS05

警示用语：

Danger

危险声明

H226,H314

危险分类

Flam. Liq. 3 - Skin Corr. 1B

补充剂危害

EUH014

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

102.2 °F - closed cup

闪点(°C)

39 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SHBN7849
SHBN5076
SHBM9950
SHBH2295V
SHBF9619V

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Silyloxyamines as sources of silyl radicals: ESR spin-trapping, laser flash photolysis investigation, and photopolymerization ability.
Versace DL, et al.
Journal of Physical Organic Chemistry, 24(4), 342-350 (2011)
Photoinduced Rearrangement Reaction of 2-(Pentamethyldisilanyloxymethyl) phenylpentamethyldisilane.
Park SK and Gong SY
Bull. Korean Chem. Soc., 31(3), 731-734 (2010)
Silyloxyamines as sources of silyl radicals: ESR spin-trapping, laser flash photolysis investigation, and photopolymerization ability.
Versace DL, et al.
Journal of Physical Organic Chemistry, 24(4), 342-350 (2011)

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