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Merck

483745

Sigma-Aldrich

cubes, contains mineral oil, 99.9% trace metals basis

别名:

Sodium metal

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100 G
$204.00
500 G
$734.00

$204.00


国内现货,预计发货时间2025年4月09日详情


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100 G
$204.00
500 G
$734.00

About This Item

经验公式(希尔记法):
Na
CAS号:
分子量:
22.99
MDL编号:
UNSPSC代码:
12352300
PubChem化学物质编号:
NACRES:
NA.22

$204.00


国内现货,预计发货时间2025年4月09日详情


获取大包装报价

蒸汽压

1 mmHg ( 440 °C)

质量水平

方案

99.9% trace metals basis

表单

cubes

包含

mineral oil

反应适用性

reagent type: reductant

电阻率

4.69 μΩ-cm, 20°C

沸点

883 °C (lit.)

mp

97.8 °C (lit.)

SMILES字符串

[Na]

InChI

1S/Na

InChI key

KEAYESYHFKHZAL-UHFFFAOYSA-N

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一般描述

钠可用作烯烃和炔烃双功能化的还原剂。也用于Bouveault-Blanc还原反应。[1]

应用

金属钠可用作反应(例如伯奇还原反应)中的还原剂。[2]

象形图

FlameCorrosion

警示用语:

Danger

危险声明

危险分类

Skin Corr. 1B - Water-react 1

补充剂危害

储存分类代码

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

闪点(°F)

179.6 °F

闪点(°C)

82 °C


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Use of Sodium Metal in the Birch Reduction of Aromatic Compounds1.
Dryden Jr HL, et al.
The Journal of Organic Chemistry, 26(9), 3237-3245 (1961)
Recent advances in the use of sodium dispersion for organic synthesis
De PB
Synthesis, 53, 3180-3192 (2021)
Andrew Mente et al.
The New England journal of medicine, 371(7), 601-611 (2014-08-15)
Higher levels of sodium intake are reported to be associated with higher blood pressure. Whether this relationship varies according to levels of sodium or potassium intake and in different populations is unknown. We studied 102,216 adults from 18 countries. Estimates
Supriya S Jalimarada et al.
Investigative ophthalmology & visual science, 54(6), 4330-4340 (2013-06-08)
Mutations in SLC4A11, a member of the SLC4 superfamily of bicarbonate transporters, give rise to corneal endothelial cell dystrophies. SLC4A11 is a putative Na⁺ borate and Na⁺:OH⁻ transporter. Therefore we ask whether SLC4A11 in corneal endothelium transports borate (B[OH]₄⁻), bicarbonate
Nicole Li et al.
American heart journal, 166(5), 815-822 (2013-11-02)
Cardiovascular diseases are the leading cause of death and disability in China. High blood pressure caused by excess intake of dietary sodium is widespread and an effective sodium reduction program has potential to improve cardiovascular health. This study is a

Questions

1–3 of 3 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. This product comes inside a metallic can. What's the correct procedure to open it? what atmosphere is inside? Can it be opened outside a glove box? (the metal can, not the glass container inside)

    1 answer
    1. Please open the metallic canister using a commercially available can opener. The atmosphere inside the canister is air. However, it is important to note that the product (metallic sodium) is stored in mineral oil, which serves to protect it from moisture and air. The metallic canister can be opened outside a glove box due to the presence of mineral oil.

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