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500 MG
$304.00
About This Item
经验公式（希尔记法）:
C5H12N2
CAS号:
分子量:
100.16
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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质量水平
方案
97%
表单
liquid
旋光性
[α]20/D +20°, c = 1 in chloroform
折射率
n20/D 1.482 (lit.)
沸点
65 °C/11 mmHg (lit.)
密度
0.933 g/mL at 25 °C (lit.)
官能团
amine
SMILES字符串
NC[C@@H]1CCCN1
InChI
1S/C5H12N2/c6-4-5-2-1-3-7-5/h5,7H,1-4,6H2/t5-/m0/s1
InChI key
AUKXFNABVHIUAC-YFKPBYRVSA-N
一般描述
(S)-(+)-2-(Aminomethyl)pyrrolidine is a chiral vicinal diamine.
应用
用于合成具有抗癌活性的化合物。[1]
(S)-(+)-2-(Aminomethyl)pyrrolidine can be used as an organocatalyst:
It can also be used as a reactant to prepare Schiff base metal complexes with pyrrolidine fragment as a ligand in asymmetric synthesis.[4]
- For the asymmetric transformation of (S)-alanine.[2]
- In the asymmetric α-fluorination of linear and branched aldehydes using N-fluorobenzenesulfonamide as the fluorinating agent.[3]
It can also be used as a reactant to prepare Schiff base metal complexes with pyrrolidine fragment as a ligand in asymmetric synthesis.[4]
警示用语：
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
116.6 °F - closed cup
闪点(°C)
47 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Dioxovanadium (V) complexes of Schiff bases derived from S-(+)-2-(aminomethyl) pyrrolidine and aromatic o-hydroxycarbonyl compounds: Synthesis, characterization and structure
Kwiatkowski E, et al.
Polyhedron, 25(15), 2809-2814 (2006)
K Morikawa et al.
Journal of pharmaceutical sciences, 80(9), 837-842 (1991-09-01)
The optical isomers of 2-aminomethylpyrrolidine(1,1-cyclobutane- dicarboxylato)platinum(II) (DWA2114, 1), which has potent antitumor activity against various tumors, were synthesized. They were examined for antitumor activity against Colon 26 carcinoma in a sc-iv system, and changes in urinary protein and sugar levels
Direct asymmetric α-fluorination of aldehydes
Steiner DD, et al.
Angewandte Chemie (International ed. in English), 44(24), 3706-3710 (2005)
Asymmetric Transformation of Alanine via Optically Labile Imidazolines
Shibata S, et al.
Bulletin of the Chemical Society of Japan, 52(10), 2938-2941 (1979)
商品
Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.
相关内容
Chiral vicinal diamines are of tremendous interest to the synthetic chemist as they are found in many chiral catalysts and pharmaceuticals.
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