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蒸汽密度
2.9 (vs air)
蒸汽壓力
7.9 mmHg ( 20 °C)
形狀
liquid
自燃溫度
590 °F
包含
copper sulfate as stabilizer
折射率
n20/D 1.439 (lit.)
bp
69-70 °C/100 mmHg (lit.)
密度
1.09 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
C=C1CC(=O)O1
InChI
1S/C4H4O2/c1-3-2-4(5)6-3/h1-2H2
InChI 密鑰
WASQWSOJHCZDFK-UHFFFAOYSA-N
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應用
用于乙酰乙酸衍生物和杂环化合物的简易制备。[1]
訊號詞
Danger
危險聲明
危險分類
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 1
閃點(°F)
93.2 °F - closed cup
閃點(°C)
34 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
S Breda et al.
The journal of physical chemistry. A, 116(9), 2131-2140 (2012-01-26)
Diketene (C(4)H(4)O(2)) monomers were isolated in cryogenic Ar (15 K) and Xe (30 K) matrices. The infrared (IR) spectra of the freshly deposited matrices show that diketene monomers exclusively adopt the 4-methylene-oxetan-2-one form. In situ photochemical transformations of diketene were
Nazariy T Pokhodylo et al.
Journal of combinatorial chemistry, 11(3), 481-485 (2009-04-23)
A convenient synthetic protocol was elaborated for creation of combinatorial libraries of 1-(R(1)-phenyl)-5-methyl-N-R(2)-1H-1,2,3-triazole-4-carboxamides. As starting materials, commercially available or readily prepared azides, amines, and diketene were selected for the reaction which has proceeded in a one-pot system with high yields
Ahmad Shaabani et al.
Journal of combinatorial chemistry, 11(3), 375-377 (2009-03-14)
In this work, 1,2,3,4,5,8-hexahydro-1,3,7-trimethyl-2,4-dioxopyrido[2,3-d]pyrimidine-6-carboxamide derivatives were synthesized in a simple and efficient method from the four-component condensation reaction of diketene, an aliphatic or aromatic amine, an aromatic aldehyde, and 6-amino-1,3-dimethyluracil in the presence of a catalytic amount of p-toluenesulfonic acid
Identification of essential amino acid residues in clostridium histolyticum collagenase using chemical modification reactions.
M D Bond et al.
Biochemical and biophysical research communications, 102(1), 243-249 (1981-09-16)
A Jonas et al.
Biochemistry, 24(14), 3508-3513 (1985-07-02)
Discoidal complexes of human apolipoprotein A-I-egg phosphatidylcholine-cholesterol were prepared by the sodium cholate dialysis procedure and were reacted to varying extents with the amino group reagents citraconic anhydride, diketene, and formaldehyde in the presence of sodium borohydride. Modification of positive
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