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Merck

422363

Sigma-Aldrich

双乙烯酮

contains copper sulfate as stabilizer

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About This Item

经验公式(希尔记法):
C4H4O2
CAS号:
分子量:
84.07
Beilstein:
104541
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
价格与库存信息目前不能提供

蒸汽密度

2.9 (vs air)

蒸汽壓力

7.9 mmHg ( 20 °C)

形狀

liquid

自燃溫度

590 °F

包含

copper sulfate as stabilizer

折射率

n20/D 1.439 (lit.)

bp

69-70 °C/100 mmHg (lit.)

密度

1.09 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

C=C1CC(=O)O1

InChI

1S/C4H4O2/c1-3-2-4(5)6-3/h1-2H2

InChI 密鑰

WASQWSOJHCZDFK-UHFFFAOYSA-N

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應用

用于乙酰乙酸衍生物和杂环化合物的简易制备。[1]

象形圖

FlameSkull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

93.2 °F - closed cup

閃點(°C)

34 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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S Breda et al.
The journal of physical chemistry. A, 116(9), 2131-2140 (2012-01-26)
Diketene (C(4)H(4)O(2)) monomers were isolated in cryogenic Ar (15 K) and Xe (30 K) matrices. The infrared (IR) spectra of the freshly deposited matrices show that diketene monomers exclusively adopt the 4-methylene-oxetan-2-one form. In situ photochemical transformations of diketene were
Nazariy T Pokhodylo et al.
Journal of combinatorial chemistry, 11(3), 481-485 (2009-04-23)
A convenient synthetic protocol was elaborated for creation of combinatorial libraries of 1-(R(1)-phenyl)-5-methyl-N-R(2)-1H-1,2,3-triazole-4-carboxamides. As starting materials, commercially available or readily prepared azides, amines, and diketene were selected for the reaction which has proceeded in a one-pot system with high yields
Ahmad Shaabani et al.
Journal of combinatorial chemistry, 11(3), 375-377 (2009-03-14)
In this work, 1,2,3,4,5,8-hexahydro-1,3,7-trimethyl-2,4-dioxopyrido[2,3-d]pyrimidine-6-carboxamide derivatives were synthesized in a simple and efficient method from the four-component condensation reaction of diketene, an aliphatic or aromatic amine, an aromatic aldehyde, and 6-amino-1,3-dimethyluracil in the presence of a catalytic amount of p-toluenesulfonic acid
Identification of essential amino acid residues in clostridium histolyticum collagenase using chemical modification reactions.
M D Bond et al.
Biochemical and biophysical research communications, 102(1), 243-249 (1981-09-16)
A Jonas et al.
Biochemistry, 24(14), 3508-3513 (1985-07-02)
Discoidal complexes of human apolipoprotein A-I-egg phosphatidylcholine-cholesterol were prepared by the sodium cholate dialysis procedure and were reacted to varying extents with the amino group reagents citraconic anhydride, diketene, and formaldehyde in the presence of sodium borohydride. Modification of positive

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