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品質等級
反應適用性
reaction type: Grignard Reaction
濃度
0.5 M in THF
bp
65 °C
密度
0.937 g/mL at 25 °C
SMILES 字串
Br[Mg]CCC=C
InChI
1S/C4H7.BrH.Mg/c1-3-4-2;;/h3H,1-2,4H2;1H;/q;;+1/p-1
InChI 密鑰
SMLLHQBZPPSOSR-UHFFFAOYSA-M
應用
可参与钌催化剂协助的环化反应的合成结构单元。
用于由 L-酒石酸合成 (–)-muricatacin 的非对映选择性关键步骤。
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react 1
標靶器官
Central nervous system, Respiratory system
安全危害
儲存類別代碼
4.3 - Hazardous materials which set free flammable gases upon contact with water
水污染物質分類(WGK)
WGK 3
閃點(°F)
-22.0 °F - closed cup
閃點(°C)
-30 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves
其他客户在看
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The combination of alkene metathesis and beta-fragmentation offers an efficient entry into (Z)-configured medium-ring cycloalkenes. The versatility of this method is demonstrated by the total synthesis of Periplanone C, a semiochemical of Periplaneta americana. [reaction: see text]
Organic letters, 6(8), 1329-1331 (2004-04-09)
A concise synthesis of the potent nAChR agonist (+)-anatoxin-a (1) has been completed in a series of only nine chemical operations and 27% overall yield from commercially available D-methyl pyroglutamate (4). The synthesis features a novel procedure for the diastereoselective
Organic letters, 6(1), 87-89 (2004-01-03)
[reaction: see text] A diastereoselective total synthesis of securinine in optically pure form was achieved by employing ring-closing metathesis of the corresponding dienyne compound as a key step.
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