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Merck

407739

Sigma-Aldrich

L-叔亮氨醇

98%, for peptide synthesis

别名:

(S)-2-氨基-3,3-二甲基-1-丁醇

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About This Item

线性分子式:
(CH3)3CCH(NH2)CH2OH
分子量:
117.19
Beilstein:
3600321
MDL號碼:
分類程式碼代碼:
12352209
PubChem物質ID:
NACRES:
NA.22

product name

L-叔亮氨醇, 98%

化驗

98%

光學活性

[α]26/D +37°, c = 1.5 in ethanol

反應適用性

reaction type: solution phase peptide synthesis

mp

30-34 °C (lit.)

密度

0.9 g/mL at 25 °C (lit.)

應用

peptide synthesis

SMILES 字串

CC(C)(C)[C@H](N)CO

InChI

1S/C6H15NO/c1-6(2,3)5(7)4-8/h5,8H,4,7H2,1-3H3/t5-/m1/s1

InChI 密鑰

JBULSURVMXPBNA-RXMQYKEDSA-N

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應用

用于各种不对称反应的有用氨基酸。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

194.0 °F - closed cup

閃點(°C)

90 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Tetrahedron, 60, 4459-4473 (2004)
Sebastian P Smidt et al.
Organic letters, 6(12), 2023-2026 (2004-06-05)
[reaction: see text] New Ir-SimplePHOX complexes Ir-6-Ir-9 catalyze the quantitative, highly enantioselective hydrogenation of a range of unfunctionalized and functionalized olefins. Synthesis, catalytic results, and X-ray crystal structures are presented here.
Tetrahedron Letters, 45, 5649-5649 (2004)
Heng Wang et al.
Chirality, 27(8), 523-531 (2015-04-25)
A novel pyridineoxazoline (PyOx) containing helical polymer, poly{(-)-(S)-4-tert-butyl-2-[5-(4-tert-butylphenyl)-3-vinylpyridin-2-yl]-oxazoline} (PA), was designed and synthesized to approach the effect of chain conformation on the catalytic property. Its complex with Cu(OTf)(2) , i.e., Cu(II)-PA, was employed to catalyze the homogeneous Diels-Alder (D-A) reaction

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