407690

N-(苄氧基)氨基甲酸叔丁酯

99%

• 线性分子式: C₆H₅CH₂ONHCO₂C(CH₃)₃
• CAS号: 79722-21-7
• 分子量: 223.27
• MDL编号: MFCD00191873
• UNSPSC代码: 12352100
• PubChem化学物质编号: 24865479

属性

• 质量水平: 100
• 方案: 99%
• mp: 45-47 °C (lit.)
• 官能团: amine; phenyl
• SMILES字符串: CC(C)(C)OC(=O)NOCc1ccccc1
• InChI: 1S/C12H17NO3/c1-12(2,3)16-11(14)13-15-9-10-7-5-4-6-8-10/h4-8H,9H2,1-3H3,(H,13,14)
• InChI key: MZNBNPWFHGWAGH-UHFFFAOYSA-N

说明

一般描述

tert-Butyl N-(benzyloxy)carbamate (tert-butyl benzyloxycarbamate), a protected hydroxylamine,[1] is an N-alkyl-N-benzyloxy carbamate.[2] Its C-N cross coupling reaction with fluorescein ditriflate has been reported.[1] It participates in facile intramolecular cyclization with various carbon nucleophiles to afford functionalized 5- and 6-membered protected cyclic hydroxamic acids.[2]

应用

tert-Butyl N-(benzyloxy)carbamate was used in the preparation of seven-membered cyclic hydroxamic acids.[2] It may be used in the synthesis of 2-(N-formyl-N-hydroxyamino) ethylphosphonate (IPP).[3]

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves