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About This Item
经验公式（希尔记法）:
C6H11NS2
CAS号:
分子量:
161.29
MDL號碼:
分類程式碼代碼:
12352005
PubChem物質ID:
NACRES:
NA.22
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化驗
≥98.0%
形狀
solid
光學活性
[α]20/D -37±3°, c = 1 in chloroform
光學純度
ee: ≥99:1 (LC)
mp
69-71 °C
SMILES 字串
CC(C)[C@H]1CSC(=S)N1
InChI
1S/C6H11NS2/c1-4(2)5-3-9-6(8)7-5/h4-5H,3H2,1-2H3,(H,7,8)/t5-/m1/s1
InChI 密鑰
CWIZUGZKLJDJLE-RXMQYKEDSA-N
應用
具有高度选择性和有效性的手性助剂，与二异丁基氢化铝发生还原裂解反应可直接还原为相应的醛和手性助剂。
(S)-4-Isopropylthiazolidine-2-thione may be used as a chiral auxiliary for the stereochemical induction at the phosphorus atom during the diastereoselective synthesis of aryloxy phosphoramidate prodrugs of 3′-deoxy-2′,3′-didehydrothymidine monophosphate (d4TMP).
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Diastereoselective synthesis of aryloxy phosphoramidate prodrugs of 3'-deoxy-2', 3'-didehydrothymidine monophosphate.
Roman CA, et al.
Journal of Medicinal Chemistry, 53(21), 7675-7681 (2010)
M T Crimmins et al.
Organic letters, 2(6), 775-777 (2001-02-07)
[formula: see text] Asymmetric aldol additions using chlorotitanium enolates of thiazolidinethione propionates proceed with high diastereoselectivity for the "Evans" or "non-Evans" syn product depending on the nature and amount of the base used. With (-)-sparteine as the base, selectivities of
Velazquez. F.; Olivo, H. F.
Current Organic Chemistry, 6, 303-303 (2002)
相关内容
The asymmetric aldol reaction mediated by chiral auxiliaries is considered to be one of the most important methods for asymmetric C-C bond formation.
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