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Merck
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文件

389439

Sigma-Aldrich

1-芘甲醇

98%

别名:

1-羟甲基芘, 1-（1-羟甲基）芘

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About This Item

经验公式（希尔记法）:
C17H12O
CAS号:
24463-15-8
分子量:
232.28
MDL號碼:
MFCD00029252
分類程式碼代碼:
12352100
PubChem物質ID:
24864285
NACRES:
NA.22

化驗

98%

形狀

solid

mp

123-126 °C (lit.)

SMILES 字串

OCc1ccc2ccc3cccc4ccc1c2c34

InChI

1S/C17H12O/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-9,18H,10H2

InChI 密鑰

NGDMLQSGYUCLDC-UHFFFAOYSA-N

相关类别

應用

1-芘乙醇可用于：
  • 合成腺苷-5′ 的钳形苯桥接荧光选择性传感器-三磷酸盐 (ATP) 检测。
  • 作为合成芘端聚甲基丙烯酸缩水甘油酯聚合物的起始原料。
  • 作为合成芘核心星形聚合物的引发剂。
  • 合成医药和农药领域的重要中间体 1-芘甲醛。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

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Highly efficient oxidation of alcohols to carbonyl compounds in the presence of molecular oxygen using a novel heterogeneous ruthenium catalyst.
Ji H, et al.
Tetrahedron Letters, 43(40), 7179-7183 (2002)
Walter Meinl et al.
Pharmacogenetics, 12(9), 677-689 (2002-12-05)
Various enzymatically formed sulfuric acid esters are chemically reactive and mutagenic. This metabolic activation pathway is not detected in standard in-vitro mutagenicity test systems. We describe the construction of Salmonella typhimurium TA1538-derived strains expressing alloenzymes *1, *2, *3, *5, *6
H Glatt et al.
Chemico-biological interactions, 109(1-3), 195-219 (1998-05-05)
Sulfation is a common final step in the biotransformation of xenobiotics and is traditionally associated with inactivation. However, the sulfate group is electron-withdrawing and may be cleaved off heterolytically in some molecules leading to electrophilic cations which may form adducts
H Glatt et al.
Chemico-biological interactions, 92(1-3), 305-319 (1994-06-01)
1-Hydroxymethylpyrene (HMP) is activated to a potent mutagen, detectable in Salmonella typhimurium, in the presence of hepatic cytosol, cofactor for sulfotransferases, and chloride anions. The number of induced mutations is linear to the amount of cytosol used over a wide
Y J Surh et al.
Carcinogenesis, 11(9), 1451-1460 (1990-09-01)
Our previous studies on 7-hydroxymethyl-12-methylbenz[a]anthracene and 6-hydroxymethylbenzo[a]pyrene showed that cytosolic sulfotransferase activity plays a major role in the formation of hepatic benzylic DNA and RNA adducts by these carcinogens in rats. In the present study, we found similar sulfotransferase activity
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