376876

N-甲氧基-N-甲基(三苯基正膦亚基)乙酰胺

98%

• 别名: (N-甲氧基甲基氨基羰基亚甲基)三苯基正膦
• 线性分子式: (C₆H₅)₃P=CHCON(OCH₃)CH₃
• CAS号: 129986-67-0
• 分子量: 363.39
• Beilstein: 4198472
• MDL编号: MFCD00134433
• UNSPSC代码: 12352002
• PubChem化学物质编号: 24863472
• NACRES: NA.22

属性

• 方案: 98%
• 反应适用性: reaction type: C-C Bond Formation
• mp: 173-175 °C (lit.)
• 官能团: amine; phosphine
• SMILES字符串: CON(C)C(=O)C=P(c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C22H22NO2P/c1-23(25-2)22(24)18-26(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21/h3-18H,1-2H3
• InChI key: DGBLSOOPDBHHRX-UHFFFAOYSA-N

说明

应用

Reactant for:

• Synthesis of electron-deficient alkenes via stereoselective olefination of N-sulfonyl imines
• Phosphine-catalyzed asymmetric addition reactions
• Cysteine-catalyzed enantioselective intramolecular Rauhut-Currier reaction
• Wittig olefination
• Synthesis of aigialomycin D, a Protein Kinase inhibitor and a potential anticancer agent

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves