365270

α-溴苯乙酸甲酯

97%

• 线性分子式: C₆H₅CH(Br)CO₂CH₃
• CAS号: 3042-81-7
• 分子量: 229.07
• MDL编号: MFCD00013535
• UNSPSC代码: 12352100
• PubChem化学物质编号: 24862500
• NACRES: NA.22

属性

• 质量水平: 200
• 方案: 97%
• 表单: liquid
• 折射率: n20/D 1.553 (lit.)
• 沸点: 113 °C/3 mmHg (lit.)
• 密度: 1.455 g/mL at 25 °C (lit.)
• 官能团: bromo; ester; phenyl
• 储存温度: 2-8°C
• SMILES字符串: COC(=O)C(Br)c1ccccc1
• InChI: 1S/C9H9BrO2/c1-12-9(11)8(10)7-5-3-2-4-6-7/h2-6,8H,1H3
• InChI key: NHFBYYMNJUMVOT-UHFFFAOYSA-N

说明

一般描述

Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.[1]

应用

Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA).[2] It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.[3]

安全信息

• 象形图: GHS05
• 警示用语：: Danger
• 危险声明: H314
• 预防措施声明: P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363 - P405
• 危险分类: Skin Corr. 1B
• 储存分类代码: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• 闪点(°F): 235.4 °F - closed cup
• 闪点(°C): 113 °C - closed cup
• 个人防护装备: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter