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方案
98%
表单
solid
mp
66-68 °C (lit.)
官能团
ketone
phenyl
SMILES字符串
O=C(CCCC(=O)c1ccccc1)c2ccccc2
InChI
1S/C17H16O2/c18-16(14-8-3-1-4-9-14)12-7-13-17(19)15-10-5-2-6-11-15/h1-6,8-11H,7,12-13H2
InChI key
YOLLTWVIOASMFW-UHFFFAOYSA-N
一般描述
1,3-Dibenzoylpropane is a 1,3-diaroylpropane. 1,3-Dibenzoylpropane is formed during hydroxocobalt(III) Schiff base complexes catalyzed selective aldol reaction of dibenzoylmethanes with formaldehyde in methanol.[1]
应用
1,3-Dibenzoylpropane may be used in the electrochemical synthesis of cis-1,2-diphenyl-1,2-cyclopentanediol, via reduction in acetonitrile.[2]
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Highly selective aldol reaction of dibenzoylmethanes with formaldehyde catalyzed by cobalt Schiff base complex under neutral conditions.
Maruyama K, et al.
Tetrahedron Letters, 36(31), 5609-5612 (1995)
Electrochemical cyclization: II. Intramolecular pinacolization of 1, 3-dibenzoylpropane in acetonitrile.
Ammar F, et al.
J. Electroanal. Chem. Interfac. Electrochem., 53(3), 407-416 (1974)
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