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Merck

295337

Sigma-Aldrich

三氟甲烷

≥98%

别名:

HFC-23, 氟仿

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About This Item

线性分子式:
CHF3
CAS号:
分子量:
70.01
EC號碼:
MDL號碼:
分類程式碼代碼:
12142100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

2.43 (vs air)

蒸汽壓力

635 psi ( 21 °C)

化驗

≥98%

bp

−84 °C (lit.)

mp

−160 °C (lit.)

SMILES 字串

FC(F)F

InChI

1S/CHF3/c2-1(3)4/h1H

InChI 密鑰

XPDWGBQVDMORPB-UHFFFAOYSA-N

包裝

Supplied in a carbon steel lecture bottle with a CGA180M/CGA110F needle valve installed.

Compatible with the following:
  • Aldrich® lecture-bottle station systems
  • Aldrich® lecture-bottle gas regulators

其他說明

法律資訊

Aldrich is a registered trademark of Sigma-Aldrich Co. LLC

排氣閥

产品编号
说明
价格

軟管倒鉤

产品编号
说明
价格

象形圖

Gas cylinder

訊號詞

Warning

危險聲明

防範說明

危險分類

Press. Gas Liquefied gas

儲存類別代碼

2A - Gases

水污染物質分類(WGK)

WGK 1

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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分析证书(COA)

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Alessandro Zanardi et al.
Journal of the American Chemical Society, 133(51), 20901-20913 (2011-12-06)
We have found the first reaction of direct cupration of fluoroform, the most attractive CF(3) source for the introduction of the trifluoromethyl group into organic molecules. Treatment of CuX (X = Cl, Br, I) with 2 equiv of MOR (M
Naleen B Jayaratna et al.
Inorganic chemistry, 52(4), 1691-1693 (2013-02-02)
Silver and copper ethylene adducts and the silver carbonyl complex of the tris(pyrazolyl)borate [HB(3,4,5-(CF(3))(3)Pz)(3)](-) (which is based on one of the most acidic pyrazoles known) have been synthesized. (13)C NMR resonance signals of metal-bound ethylene carbon atoms of [HB(3,4,5-(CF(3))(3)Pz)(3)]Ag(C(2)H(4)) and
Mark A Honey et al.
The Journal of organic chemistry, 77(3), 1396-1405 (2012-01-24)
Ethyl 2-diazo-4,4,4-trifluoro-3-oxobutanoate is a highly versatile intermediate for the synthesis of a wide range of trifluoromethyl heterocycles. With the use of rhodium(II) or copper(II) catalyzed carbene X-H insertion reactions as key steps, a diverse set of trifluoromethyl-oxazoles, -thiazoles, -imidazoles, -1,2,4-triazines
Charles S Thomoson et al.
The Journal of organic chemistry, 78(17), 8904-8908 (2013-08-13)
Fluoroform, CHF3, a non-ozone-depleting, nontoxic, and inexpensive gas can be used as a difluorocarbene source in a process for the conversion of phenols and thiophenols to their difluoromethoxy and difluorothiomethoxy derivatives. The reactions are carried out at moderate temperatures and
Shun Noritake et al.
Organic & biomolecular chemistry, 7(17), 3599-3604 (2009-08-14)
Chiral nonracemic guanidines act as Brønsted bases to generate guanidinium enolates for the enantioselective electrophilic trifluoromethylation of beta-keto esters by means of S-(trifluoromethyl)dibenzothiophenium tetrafluoroborate (Umemoto reagent) with good enantioselectivity of 60-70% range. Despite the fact that the ees are still

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