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Merck
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文件

H8706

Sigma-Aldrich

六氟苯

99%

别名:

六氟苯

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About This Item

经验公式（希尔记法）:
C6F6
CAS号:
392-56-3
分子量:
186.05
Beilstein:
1683438
EC號碼:
206-876-2
MDL號碼:
MFCD00000288
分類程式碼代碼:
12352100
PubChem物質ID:
24895528
NACRES:
NA.22

化驗

99%

形狀

liquid

折射率

n20/D 1.377 (lit.)

bp

80-82 °C (lit.)

mp

3.7-4.1 °C (lit.)

密度

1.612 g/mL at 25 °C (lit.)

SMILES 字串

Fc1c(F)c(F)c(F)c(F)c1F

InChI

1S/C6F6/c7-1-2(8)4(10)6(12)5(11)3(1)9

InChI 密鑰

ZQBFAOFFOQMSGJ-UHFFFAOYSA-N

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應用

六氟苯可与以下物质反应：
  • 在过渡金属卤化物存在下，与乙基溴化镁反应形成相应的全氟芳基镁化合物（可发生格氏反应）。
  • 在1,3-二甲基-2-咪唑烷酮（DMEU）中与适当苯酚的钠盐反应，形成六(芳氧基)苯。

它可以用于：
  • 作为合成新型钌(0)和锇(0)六氟苯配合物的配体。
  • 在存在钌催化剂时，作为闭环复分解（RCM）的溶剂和助催化剂，形成四取代烯烃。

象形圖

Flame
GHS02

訊號詞

Danger

危險聲明

H225

危險分類

Flam. Liq. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

50.0 °F - closed cup

閃點（°C）

10 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Synthesis of hexakis (aryloxy) benzenes: x-ray analysis of hexakis (phenyloxy) benzene and of the acetonitrile clathrate of hexakis (3, 5-dimethylphenyloxy) benzene
Gilmore C J, et al.
Tetrahedron Letters, 24(31), 3269-3272 (1983)
Synthesis of new ? 4-hexafluorobenzene complexes of ruthenium and osmium from atoms of the metals: crystal structure of [Ru (? 6-C 6 H 3 Me 3-1, 3, 5)(? 4-C 6 F 6)]
Martin A, et al.
Journal of the Chemical Society, (15), 2251-2255 (1994)
Benjamin W Gung et al.
The Journal of organic chemistry, 71(25), 9261-9270 (2006-12-02)
Parallel displaced and sandwich configurations of hexafluorobenzene-substituted benzene dimers are studied by ab initio molecular orbital methods up to the MP2(full)/aug-cc-pVDZ level of theory to reveal how substituents influence pi-pi interactions. Two minimum energy configurations are found, one with the
Lionel Mignion et al.
Magnetic resonance in medicine, 69(1), 248-254 (2012-03-24)
Hexafluorobenzene (HFB) and perfluoro-15-crown-5-ether (15C5) were compared as fluorine reporter probes of tissue oxygenation using (19)F MRI for dynamic assessment of muscle oxygenation, with special focus on muscle tissue toxicity of the probes, and consecutive alteration of animal behavior. The
Alain Grandbois et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(30), 9323-9329 (2008-08-30)
The asymmetric synthesis of [7]helicene was accomplished in good ee (80%) by kinetic resolution by means of asymmetric olefin metathesis. Three key factors contributed to the success of the kinetic resolution: the use of new Ru-based olefin metathesis catalysts bearing
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