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Merck
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文件

252301

Sigma-Aldrich

8-溴-1-辛烯

97%

别名:

1-Bromo-7-octene, 7-Octen-1-yl bromide, 7-Octenyl bromide

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About This Item

线性分子式:
Br(CH2)6CH=CH2
CAS号:
2695-48-9
分子量:
191.11
Beilstein:
2234481
EC號碼:
220-268-4
MDL號碼:
MFCD00000275
分類程式碼代碼:
12352100
PubChem物質ID:
24855199
NACRES:
NA.22

品質等級

100

化驗

97%

形狀

liquid

折射率

n20/D 1.467 (lit.)

密度

1.139 g/mL at 25 °C (lit.)

SMILES 字串

BrCCCCCCC=C

InChI

1S/C8H15Br/c1-2-3-4-5-6-7-8-9/h2H,1,3-8H2

InChI 密鑰

SNMOMUYLFLGQQS-UHFFFAOYSA-N

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應用

8-Bromo-1-octene has been used in preparation of polymerizable ligand, required for the synthesis of quantum dot-labelled polymer beads. Grignard reagent derived from 8-bromo-1-octene has been used in the synthesis of (2S,3S,5R)-5-[(1R)-1-hydroxy-9-decenyl]-2-pentyltetrahydro-3-furanol. It has been used as building block in natural product synthesis.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

172.4 °F - closed cup

閃點（°C）

78 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Enantiocontrolled synthesis of C-19 tetrahydrofurans isolated from the marine alga Notheia anomala.
Garci'a C, et al.
Tetrahedron Letters, 41(21), 4127-4130 (2000)
Christophe Dubost et al.
Organic letters, 8(22), 5137-5140 (2006-10-20)
The total synthesis of the polyhydroxylated macrolide (+)-aspicilin 5 is described using as a key step a highly diastereoselective allylation of aldehyde 6 with the uniquely functionalized allylstannane 1. (+)-Aspicilin is obtained in 18 steps and 10% overall yield. [structure:
Paul O'Brien et al.
Chemical communications (Cambridge, England), (20)(20), 2532-2533 (2003-11-05)
CdSe quantum dots with polymerisable ligands have been incorporated into polystyrene beads, via a suspension polymerisation reaction, as a first step towards the optical encoding of solid supports for application in solid phase organic chemistry.
Carolyn A Leverett et al.
The Journal of organic chemistry, 71(22), 8591-8601 (2006-10-27)
cis-2-Methyl-6-substituted piperidin-3-ol alkaloids of the Cassia and Prosopis species are readily prepared by a combination of an aza-Achmatowicz oxidative rearrangement and dihydropyridone reduction followed by a stereoselective allylsilane addition to a N-sulfonyliminium ion. The stereochemical outcome of the reduction reaction

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