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Merck

227110

Sigma-Aldrich

乙酰丙酮钒(III)

97%

别名:

2,4-戊二酮 钒(III) 衍生物

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10 G
$101.00
50 G
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About This Item

线性分子式:
V(C5H7O2)3
CAS号:
分子量:
348.27
Beilstein:
4148970
EC 号:
MDL编号:
UNSPSC代码:
12352103
PubChem化学物质编号:
NACRES:
NA.23

$101.00


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质量水平

方案

97%

表单

powder

反应适用性

core: vanadium
reagent type: catalyst

mp

181-184 °C (lit.)

SMILES字符串

CC(=O)\C=C(\C)O[V](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.V/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

JTPOGAMSYINTGF-LNTINUHCSA-K

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应用

乙酰丙酮钒(III)可作为可溶性催化剂和氧化还原介体,使锂离子电池中的过氧化锂有效氧化。[1]它也可以用作通过化学气相沉积(CVD)技术制备二氧化钒薄膜的原料。[2]

其他说明

暴露于空气/水分时,材料表面可能变为绿色。

象形图

Skull and crossbones

警示用语:

Danger

危险分类

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Vanadium (III) Acetylacetonate as an Efficient Soluble Catalyst for Lithium-Oxygen Batteries
Zhao Q, et al.
Angewandte Chemie (International Edition in English), 131(36), 12683-12687 (2019)
Vanadium dioxide thin films prepared by chemical vapour deposition from vanadium (III) acetylacetonate
Maruyama, T and Ikuta, Y
Journal of materials science & technology, 28(18), 5073-5078 (1993)

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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