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Merck

225568

Sigma-Aldrich

四丙基溴化铵

98%

别名:

N,N,N-Tripropyl-1-propanaminium bromide

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100 G
$107.00
500 G
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About This Item

线性分子式:
(CH3CH2CH2)4N(Br)
CAS号:
分子量:
266.26
Beilstein:
3567846
EC 号:
MDL编号:
UNSPSC代码:
12352107
PubChem化学物质编号:
NACRES:
NA.22

$107.00


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质量水平

方案

98%

表单

crystals

SMILES字符串

[Br-].CCC[N+](CCC)(CCC)CCC

InChI

1S/C12H28N.BrH/c1-5-9-13(10-6-2,11-7-3)12-8-4;/h5-12H2,1-4H3;1H/q+1;/p-1

InChI key

BGQMOFGZRJUORO-UHFFFAOYSA-M

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一般描述

四丙基溴化铵(TPAB)是一种季铵盐。常作为相转移催化剂,在有机合成与各种化学反应中促进带电物质在不同相之间转移。 本品环境相容性好、操作简便、无腐蚀性、再利用方便,适宜作为有机合成材料。[1]

应用

四丙基溴化铵可作为结构导向剂:
  • 合成ZSM-5沸石作为石油和精细化工行业的重要催化剂。
  • 合成微孔和介孔材料用于电子(导电聚合物)和催化领域。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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A Facile Synthesis of Xanthene-1, 8 (2H)-dione Derivatives by Using Tetrapropylammonium Bromide as Catalyst
Poursattar Marjani A, et al.
Journal of Heterocyclic Chemistry, 55(6), 1324-1330 (2018)
Hui Wang et al.
Physical chemistry chemical physics : PCCP, 17(32), 20636-20646 (2015-07-24)
The (13)C NMR chemical shift moving upfield indicates the main model of π-holeX(-) bond between cyanuric chloride/1,3,5-triazine (3ClN/3N), which possess both the π-hole and σ-hole, and X(-). (13)C NMR and UV absorption titration in acetonitrile confirmed that the bonding abilities
Yong Peng et al.
Angewandte Chemie (International ed. in English), 54(19), 5709-5712 (2015-03-19)
The fabrication of MFI zeolite films with particular b-axis orientation is especially fascinating. Unlike the conventional alkaline or hydrofluoric acid (HF) assisted neutral synthesis route, here we develop a novel neutral synthesis solution system of TPABr/fumed silica/H2 O without the
Sarika Goel et al.
Journal of the American Chemical Society, 136(43), 15280-15290 (2014-10-15)
The encapsulation of metal clusters (Pt, Ru, Rh) within MFI was achieved by exchanging cationic metal precursors into a parent zeolite (BEA, FAU), reducing them with H2 to form metal clusters, and transforming these zeolites into daughter structures of higher
Joel G Davis et al.
The journal of physical chemistry. B, 119(29), 9417-9422 (2014-11-22)
Raman multivariate curve resolution (Raman-MCR), as well as quantum and classical calculations, are used to probe water structural changes in the hydration shells of carboxylic acids and tetraalkyl ammonium ions with various aliphatic chain lengths. The results reveal that water

Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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