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Merck

213969

Sigma-Aldrich

D-(-)-酒石酸二乙酯

≥99%

别名:

D-(-)-Tartaric acid diethyl ester

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About This Item

线性分子式:
HO2CCCH(OH)CH(OH)CO2H
CAS号:
分子量:
206.19
Beilstein:
1727143
EC號碼:
MDL號碼:
分類程式碼代碼:
12352108
PubChem物質ID:
NACRES:
NA.22

化驗

≥99%

光學活性

[α]23/D −8.5°, neat

光學純度

ee: ≥99% (GLC)

折射率

n20/D 1.446 (lit.)

bp

162 °C/19 mmHg (lit.)

密度

1.205 g/mL at 20 °C (lit.)

SMILES 字串

CCOC(=O)[C@@H](O)[C@H](O)C(=O)OCC

InChI

1S/C8H14O6/c1-3-13-7(11)5(9)6(10)8(12)14-4-2/h5-6,9-10H,3-4H2,1-2H3/t5-,6-/m0/s1

InChI 密鑰

YSAVZVORKRDODB-WDSKDSINSA-N

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應用

(-)-二乙基 D -酒石酸二乙酯可作为合成生物活性化合物(如 (-)-苦马豆素 、丁香内酯 2 和 (+)--短杆菌素)的起始物料。

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

200.1 °F - closed cup

閃點(°C)

93.4 °C - closed cup

個人防護裝備

Eyeshields, Gloves


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A new expeditious synthesis of (+)-exo-brevicomin via efficient C? C bond formation of triflates.
Kotsuki H, et al.
Tetrahedron Letters, 30(30), 3999-4000 (1989)
Radical cyclization of ?-alkoxyacrylates: A formal synthesis of (-)-kumausallene.
Lee E, et al.
Tetrahedron Letters, 39(3), 317-318 (1998)
Synthesis and absolute configuration of syringolide 2, an elicitor from Pseudomonas syringae pv. tomato.
Kuwahara S, et al.
Tetrahedron Letters, 36(18), 3201-3202 (1995)
Kimberly A Kahle et al.
Electrophoresis, 28(15), 2644-2657 (2007-06-29)
In this second study on dual-chirality microemulsions containing a chiral surfactant and a chiral oil, a less hydrophobic and lower interfacial tension chiral oil, diethyl tartrate, is employed (Part 1, Foley, J. P. et al.., Electrophoresis, DOI: 10.1002/elps.200600551). Six stereochemical
Aman Ullah et al.
Biomacromolecules, 12(10), 3826-3832 (2011-09-06)
Poultry feather quills have been extruded in a twin screw extruder with sodium sulfite treatment as a reducing agent. The effect of four different plasticizers (ethylene glycol, propylene glycol, glycerol, and diethyl tartrate) on the thermoplastic properties was then investigated.

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