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Merck

206032

Sigma-Aldrich

二氧化铂

greener alternative

别名:

二氧化铂, 亚当斯催化剂, 氧化铂, 神经干细胞 402624

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250 MG
$116.00
1 G
$318.00
5 G
$935.00
50 G
$7,650.00

$116.00


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250 MG
$116.00
1 G
$318.00
5 G
$935.00
50 G
$7,650.00

About This Item

线性分子式:
PtO2
CAS号:
分子量:
227.08
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

$116.00


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形狀

solid

品質等級

成份

Pt, 81-83%

反應適用性

core: platinum
reagent type: catalyst

環保替代產品特色

Designing Safer Chemicals
Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

表面積

≥60 m2/g

mp

450 °C (lit.)

環保替代類別

SMILES 字串

O=[Pt]=O

InChI

1S/2O.Pt

InChI 密鑰

YKIOKAURTKXMSB-UHFFFAOYSA-N

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一般說明

我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。该产品为增强型,提高了催化效率。点击此处了解更多信息。

應用

催化剂:
  • 氢肼化反应
  • 糖的氧化
  • 一氧化碳的低温氧化
  • 氧还原反应
  • 氢化反应
  • 环丙基氢解为异丙基
  • 羟基环丙烷化反应
具有最小的氢解问题的各种官能团的氢化催化剂; 用作脱氢催化剂; 用于选择性氧化伯醇。
氧化铂可用于将citernyl bromide还原为(S)-3,7-二甲基辛基溴化物。[1]

对于小规模和高通量应用,可选用ChemBeads形式(928291)

象形圖

Flame over circle

訊號詞

Danger

危險聲明

危險分類

Ox. Sol. 1

儲存類別代碼

5.1A - Strongly oxidizing hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Room-temperature discotic cholesteric and nematic phases: influence of 3, 7-dimethyloctane peripheral chain on the molecular self-assembly of radial polyalkynylbenzene.
Varshney SK
Liq. Cryst., 38(1), 53-60 (2011)
Avery, M. A.; Verlander, M. S.; Goodman, M.
The Journal of Organic Chemistry, 45, 2750-2750 (1980)
Just, G.; Wang, Z. Y.; Chan, L.
The Journal of Organic Chemistry, 53, 1030-1030 (1988)
Lee, T. B. K.; Wong, G. S. K.
The Journal of Organic Chemistry, 56, 872-872 (1991)
Development of GSKDevelopment of GSK's reagent guides ? embedding sustainability into reagent selections reagent guides ? embedding sustainability into reagent selection.
Adams JP, et al.
Green Chemistry, 15, 1542-1549 (2013)

商品

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis

相关内容

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. Below is a list of the most commonly used oxidizing and reducing agents currently available in our catalog.

Questions

1–6 of 6 Questions  
  1. What is the Department of Transportation shipping information for this product?

    1 answer
    1. Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.

      Helpful?

  2. Is Product 206032, Platinum (IV) oxide, water soluble?

    1 answer
    1. It is insoluble in water.

      Helpful?

  3. Are there any safety concerns with Product 206032, Platinum (IV) oxide?

    1 answer
    1. After exposure to hydrogen, the resulting platinum black can be pyrophoric.  Therefore, it should not be allowed to dry and all exposure to oxygen should be minimized.

      Helpful?

  4. How can Product 206032, Platinum (IV) oxide, be used as a catalyst?

    1 answer
    1. Platinum(IV) oxide can be used as a catalyst in hydrogenations.  The actual catalyst is platinum black which is formed in situ by reduction of the PtO2 by the hydrogen used for the hydrogenation.  It is especially useful for reduction at room temperature and hydrogen pressures up to 4 atmospheres.  It is suitable for the reduction of double and triple bonds, aromatic nuclei, carbonyl groups, nitro groups, and nitriles.

      Helpful?

  5. In which solvents is Product 206032, Platinum (IV) oxide, soluble?

    1 answer
    1. Per the the chemicals encyclopedia published by the Royal Society of Chemistry, 13th Edition, when freshly precipitated, Platinum(IV) Oxide is soluble in concentrated acids and dilute phosphoric acid, especially when warmed.  It is easily soluble in dilute solutions of potassium hydroxide.

      Helpful?

  6. Can the Platinum be recovered from Product 206032, Platinum (IV) oxide?

    1 answer
    1. Internet sources do indicate that Platinum can be recovered from spent catalyst by conversion to ammonium chloroplatinate using aqua regia followed by ammonia.  However, we do have a process for doing so.

      Helpful?

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