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表单
powder
反应适用性
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
环保替代产品特性
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
标记范围
5 wt. % loading
环保替代产品分类
, Enabling
SMILES字符串
[Pd]
InChI
1S/Pd
InChI key
KDLHZDBZIXYQEI-UHFFFAOYSA-N
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应用
Palladium on barium sulfate (Pd/BaSO4), also known as Rosenmund catalyst, is used for the decarboxylation of aliphatic esters for further production of biodiesel.[1] It can also be used in hydrogenation reaction.[2] Pd/BaSO4 may be used as a catalyst reservoir for the Stille cross-coupling reaction between iodobenzene and tributylphenyltin.[3]
其他说明
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Palladium on carbon-catalyzed solvent-free and solid-phase hydrogenation and Suzuki-Miyaura reaction
Monguchi Y, et al.
Tetrahedron, 67(45), 8628-8634 (2011)
Stille cross-coupling reaction using Pd/BaSO4 as catalyst reservoir
Coelho AV, et al.
Applied Organometallic Chemistry, 22(1), 39-42 (2008)
Palladium-catalyzed decarboxylation of higher aliphatic esters: Towards a new protocol to the second generation biodiesel production
Han J, et al.
Green Chemistry, 12(3), 463-467 (2010)
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