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表单
liquid
质量
packed in FEP bottles
反应适用性
reagent type: oxidant
浓度
52.9-66.8% (iodometric)
~5.5 M in decane (over molecular sieve 4Å)
折射率
n20/D 1.403
密度
0.83 g/mL at 20 °C
储存温度
2-8°C
SMILES字符串
CC(C)(C)OO
InChI
1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3
InChI key
CIHOLLKRGTVIJN-UHFFFAOYSA-N
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警示用语：
Danger
危险分类
Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3
靶器官
Respiratory system
储存分类代码
5.2 - Organic peroxides and self-reacting hazardous materials
WGK
WGK 3
闪点(°F)
109.4 °F - closed cup
闪点(°C)
43 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
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Applied Catalysis A: General, 253, 91-99 (2003)
K. Akashi et al.
The Journal of Organic Chemistry, 43, 2063-2063 (1978)
T. Katsuki et al.
Org. React., 48, 1-1 (1996)
Maxim O Ratnikov et al.
Journal of the American Chemical Society, 135(4), 1549-1557 (2013-01-10)
A general mechanism is proposed for transition metal-catalyzed oxidative Mannich reactions of N,N-dialkylanilines with tert-butyl hydroperoxide (TBHP) as the oxidant. The mechanism consists of a rate-determining single electron transfer (SET) that is uniform from 4-methoxy- to 4-cyano-N,N-dimethylanilines. The tert-butylperoxy radical
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