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Merck

184837

Sigma-Aldrich

)-2-氨基-3-甲基-1-丁醇

97%

别名:

DL-缬氨醇

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About This Item

线性分子式:
(CH3)2CHCH(NH2)CH2OH
CAS号:
分子量:
103.16
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:

化驗

97%

形狀

liquid

折射率

n20/D 1.4543 (lit.)

bp

75-77 °C/8 mmHg (lit.)

密度

0.936 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)C(N)CO

InChI

1S/C5H13NO/c1-4(2)5(6)3-7/h4-5,7H,3,6H2,1-2H3

InChI 密鑰

NWYYWIJOWOLJNR-UHFFFAOYSA-N

應用

2-氨基-3-甲基-1-丁醇被用于合成1-烯丙基-2-吡咯烷酮。 它也被用作手性亲核试剂,用于合成贝娜诺霉素-普纳米星类抗生素。在合成包含两个手性亚基的冠醚时,它被用作同手性客体化合物

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

194.0 °F - closed cup

閃點(°C)

90 °C - closed cup

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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Preparation of homochiral phenolic crown ethers containing para-substituted phenol moiety and chiral subunits derived from (S)-1-phenylethane-1, 2-diol: their chiral recognition behaviour in complexation with neutral amines.
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E Spitzer et al.
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A general approach to the regio- and stereoselective total synthesis of the benanomicin-pradimicin antibiotics (BpAs) is described. Construction of the aglycon has been achieved by 1) the diastereoselective ring-opening of a biaryl lactone by using (R)-valinol as a chiral nucleophile

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