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化驗
97%
形狀
liquid
折射率
n20/D 1.507 (lit.)
bp
187-189 °C (lit.)
密度
1.137 g/mL at 20 °C (lit.)
SMILES 字串
CC(=O)c1ccccc1F
InChI
1S/C8H7FO/c1-6(10)7-4-2-3-5-8(7)9/h2-5H,1H3
InChI 密鑰
QMATYTFXDIWACW-UHFFFAOYSA-N
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一般說明
The enantioselective reduction of 2′-fluoroacetophenone has been investigated.
應用
2′-Fluoroacetophenone was used as starting reagent in the synthesis of ascididemin.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2
儲存類別代碼
10 - Combustible liquids
水污染物質分類（WGK）
WGK 3
閃點（°F）
143.6 °F - closed cup
閃點（°C）
62 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
其他客户在看
Ida Nymann Petersen et al.
Chemical communications (Cambridge, England), 48(72), 9092-9094 (2012-08-07)
A new and convergent synthesis of ascididemin is presented. Using an anionic cascade ring closure as the key step, this natural product is obtained in 45% overall yield in just 6 steps starting from 2'-fluoroacetophenone. This new approach was extended
The enantioselective reduction of 2'-fluoroacetophenone utilizing a simplified CBS-reduction procedure.
Garrett CE, et al.
Tetrahedron Asymmetry, 13(13), 1347-1349 (2002)
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