178969

三仲丁基硼烷 溶液

1.0 M in THF

• 别名: Tris(1-methylpropyl)borane
• 线性分子式: [C₂H₅CH(CH₃)]₃B
• CAS号: 1113-78-6
• 分子量: 182.15
• MDL编号: MFCD00009325
• UNSPSC代码: 12352001
• PubChem化学物质编号: 24850784
• NACRES: NA.22

属性

• 质量水平: 100
• 反应适用性: reagent type: reductant
• 浓度: 1.0 M in THF
• 密度: 0.799 g/mL at 25 °C
• SMILES字符串: CCC(C)B(C(C)CC)C(C)CC
• InChI: 1S/C12H27B/c1-7-10(4)13(11(5)8-2)12(6)9-3/h10-12H,7-9H2,1-6H3
• InChI key: YUPAWYWJNZDARM-UHFFFAOYSA-N

说明

应用

Catalyst for:

• Allylic alkylations for synthesis of unsaturated aldehydes and alcohols
• Cis-addition of carbon-hydrogen bonds of pyrroles and thiophenes to alkynes
• Borane-induced radical reduction of alkenyl and alkynyliodanes
• Initiating polymerization for synthesis of polymethylenes and ethylene-propylene
• Asymmetric synthesis of vinylglycidols
• Asymmetric addition of alcohols to vinyl epoxides

安全信息

• 象形图: GHS02,GHS08,GHS05,GHS07
• 警示用语：: Danger
• 危险声明: H225,H314,H335,H351
• 预防措施声明: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危险分类: Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 靶器官: Respiratory system
• 补充剂危害: EUH019
• 储存分类代码: 3 - Flammable liquids
• WGK: WGK 1
• 闪点(°F): 1.4 °F
• 闪点(°C): -17 °C